Research Article
BibTex RIS Cite

Year 2020, , 35 - 43, 15.06.2020

Derya Ünlü

https://doi.org/10.38088/jise.713852

Abstract

References

  • [1] Huth E., Muthu S., Ruff L., Brant J. (2014). Feasibility Assessment of Pervaporation for Desalinating High- Salinity Brines. Journal of Water Reuse & Desalination, 4(2): 109-124.
  • [2] Selim, A., Toth, J.A., Haaz, E., Fozer, D., Szanyi, A., Hegyesi, N., Mizsey, P. (2019). Preparation and characterization of PVA/GA/Laponite membranes to enhance pervaporation desalination performance. Separation and Purification Technology, 221:201-210.
  • [3] Assabumrungrat, S., Phongpatthanapanich, J., Praserthdam, P., Tagawa, T., Goto, S. (2003). Theoretical study on the synthesis of methyl acetate from methanol and acetic acid in pervaporation membrane reactors: effect of continuous-flow modes. Chemical Engineering Journal, 95(1-3): 57-65.
  • [4] Park, B.G., Tsotsis, T.T. (2004). Models and experiments with pervaporation membrane reactors integrated with an adsorbent system. Chemical Engineering and Processing: Process Intensification, 43(9):1171-1180.
  • [5] Unlu, D., Hilmioglu, N.D. (2014). Pervaporation catalytic membrane reactor study for the production of ethyl acetate using Zr(SO4)2.4H2O coated chitosan membrane. Journal of Chemical Technology and Biotechnology, 91(1):122-130.
  • [6] Kavitha, J., Rajalakshmi, M., Phani, A.R., Padaki, M. (2019). Pretreatment processes for seawater reverse osmosis desalination systems—A review. Journal of Water Process Engineering, 32:100926.
  • [7] Huang, R.Y.M. (1991). Pervaporation Membrane Separation Processes, Elsevier, Science Publishers BV, Amsterdam, 1st Edition, 549 p. ISBN-0444882278.
  • [8] Smitha, B., Suhanya, D., Sridhar, S., Ramakrishna, M. (2004). Separation of organic–organic mixtures by pervaporation—a review. Journal of Membrane Science, 241(1):1-21.
  • [9] Wijmans, J. G., Baker R. W. (1995). The solution-diffusion model: a review. Journal of Membrane Science, 107(1-2):1-21.
  • [10] Austria, H.F.M., Lecaros, R.L.G., Hung, W.-S., Tayo, L.L., Hu, C.-C., Tsai, H.-A., Lai, J.-Y. (2019). Investigation of salt penetration mechanism in hydrolyzed polyacrylonitrile asymmetric membranes for pervaporation desalination. Desalination, 463:32–39.
  • [11] Venkatesulu, G., Babu, P.K., Maruthi, Y., Rao, U.S.K., Subha, M.C.S., Rao, K.C. (2016). Composite Membranes Comprising of Hydroxypropyl Cellulose - Poly(VinylAlcohol) Incorporated with Inorganic Fillers for Dehydration of Ethanol by Pervaporation. Journal of Advanced Chemical Sciences, 2(1): 174-179.
  • [12] Zhang, X.H., Liu, Q.L., Xiong, Y., Zhu, A.M., Chen, Y., Zhang, Q.G. (2009). Pervaporation Dehydration of Ethyl Acetate/Ethanol/Water Azeotrope Using Chitosan/Poly (vinyl pyrrolidone) Blend Membranes. Journal of Membrane Science, 327:274–280.
  • [13] Guirguis, O.W., Moselhey, M.T.H. (2011). Optical study of poly(vinyl alcohol)/hydroxypropyl methylcellulose blends. Journal of Materials Science, 46(17):5775–5789.
  • [14] Rao, K.C., Subha, M.C.S., Reddy, C.S., Babu, P.K., Sudhakar, K., Prabhakar, M.N., Maruthi, Y., and U. Rao, U.S.K. (2013). Miscibility Studies of Hydroxyethyl Cellulose and Poly (Vinylpyrrolidone) Blends. International Journal of Basic and Applied Chemical Sciences, 3(1): 73-83.
  • [15] Elkader, M.F.H.A., Abu-Abdeen, M. (2012). Thermal and Mechanical Studies of PVP/2-HEC Blend Films. Australian Journal of Basic and Applied Sciences, 6(13): 454-462.
  • [16] Zhu, T., Luo, Y., Lin, Y., Li, Q., Yu, P., Zeng, M. (2010). Study of pervaporation for dehydration of caprolactam through blend NaAlg–poly(vinyl pyrrolidone) membranes on PAN supports. Separation and Purification Technology, 74(2):242–252.
  • [17] Ding, M., Xu, H., Chen, W., Yang, G., Kong, Q., Ng, D., Xie, Z. (2020). 2D laminar maleic acid-crosslinked MXene membrane with tunable nanochannels for efficient and stable pervaporation desalination. Journal of Membrane Science, 600: 117871.

Pervaporative Desalination of Water Using Hydroxypropyl methylcellulose / Polyvinylpyrrolidone Blend Membranes

Year 2020, , 35 - 43, 15.06.2020

Derya Ünlü

https://doi.org/10.38088/jise.713852

Abstract

The pervaporation is a promising process to achieve highly efficient desalination performance. In this study, Hydroxypropyl methylcellulose (HPMC) and Polyvinylpyrrolidone (PVP) polymers were chosen in the synthesis of blend membranes and used for pervaporative desalination process. The chemical structure and thermal stability of membranes were analyzed by using Fourier-transform infrared spectroscopy (FTIR) and Thermogravimetric analysis (TGA), respectively. The effects of PVP ratio in membrane and operation temperature on the flux and salt rejection were examined. The highest separation efficiency was acquired as water flux of 4.86 kg/m2h and a salt rejection of 99.9% using 50 wt% PVP ratio at 40 °C. The obtained results show that HPMC/PVP blend membrane has a great potential for water desalination via pervaporation.

Keywords

Desalination Hydroxypropyl Methylcellulose Membrane Pervaporation Polyvinylpyrrolidone

References

  • [1] Huth E., Muthu S., Ruff L., Brant J. (2014). Feasibility Assessment of Pervaporation for Desalinating High- Salinity Brines. Journal of Water Reuse & Desalination, 4(2): 109-124.
  • [2] Selim, A., Toth, J.A., Haaz, E., Fozer, D., Szanyi, A., Hegyesi, N., Mizsey, P. (2019). Preparation and characterization of PVA/GA/Laponite membranes to enhance pervaporation desalination performance. Separation and Purification Technology, 221:201-210.
  • [3] Assabumrungrat, S., Phongpatthanapanich, J., Praserthdam, P., Tagawa, T., Goto, S. (2003). Theoretical study on the synthesis of methyl acetate from methanol and acetic acid in pervaporation membrane reactors: effect of continuous-flow modes. Chemical Engineering Journal, 95(1-3): 57-65.
  • [4] Park, B.G., Tsotsis, T.T. (2004). Models and experiments with pervaporation membrane reactors integrated with an adsorbent system. Chemical Engineering and Processing: Process Intensification, 43(9):1171-1180.
  • [5] Unlu, D., Hilmioglu, N.D. (2014). Pervaporation catalytic membrane reactor study for the production of ethyl acetate using Zr(SO4)2.4H2O coated chitosan membrane. Journal of Chemical Technology and Biotechnology, 91(1):122-130.
  • [6] Kavitha, J., Rajalakshmi, M., Phani, A.R., Padaki, M. (2019). Pretreatment processes for seawater reverse osmosis desalination systems—A review. Journal of Water Process Engineering, 32:100926.
  • [7] Huang, R.Y.M. (1991). Pervaporation Membrane Separation Processes, Elsevier, Science Publishers BV, Amsterdam, 1st Edition, 549 p. ISBN-0444882278.
  • [8] Smitha, B., Suhanya, D., Sridhar, S., Ramakrishna, M. (2004). Separation of organic–organic mixtures by pervaporation—a review. Journal of Membrane Science, 241(1):1-21.
  • [9] Wijmans, J. G., Baker R. W. (1995). The solution-diffusion model: a review. Journal of Membrane Science, 107(1-2):1-21.
  • [10] Austria, H.F.M., Lecaros, R.L.G., Hung, W.-S., Tayo, L.L., Hu, C.-C., Tsai, H.-A., Lai, J.-Y. (2019). Investigation of salt penetration mechanism in hydrolyzed polyacrylonitrile asymmetric membranes for pervaporation desalination. Desalination, 463:32–39.
  • [11] Venkatesulu, G., Babu, P.K., Maruthi, Y., Rao, U.S.K., Subha, M.C.S., Rao, K.C. (2016). Composite Membranes Comprising of Hydroxypropyl Cellulose - Poly(VinylAlcohol) Incorporated with Inorganic Fillers for Dehydration of Ethanol by Pervaporation. Journal of Advanced Chemical Sciences, 2(1): 174-179.
  • [12] Zhang, X.H., Liu, Q.L., Xiong, Y., Zhu, A.M., Chen, Y., Zhang, Q.G. (2009). Pervaporation Dehydration of Ethyl Acetate/Ethanol/Water Azeotrope Using Chitosan/Poly (vinyl pyrrolidone) Blend Membranes. Journal of Membrane Science, 327:274–280.
  • [13] Guirguis, O.W., Moselhey, M.T.H. (2011). Optical study of poly(vinyl alcohol)/hydroxypropyl methylcellulose blends. Journal of Materials Science, 46(17):5775–5789.
  • [14] Rao, K.C., Subha, M.C.S., Reddy, C.S., Babu, P.K., Sudhakar, K., Prabhakar, M.N., Maruthi, Y., and U. Rao, U.S.K. (2013). Miscibility Studies of Hydroxyethyl Cellulose and Poly (Vinylpyrrolidone) Blends. International Journal of Basic and Applied Chemical Sciences, 3(1): 73-83.
  • [15] Elkader, M.F.H.A., Abu-Abdeen, M. (2012). Thermal and Mechanical Studies of PVP/2-HEC Blend Films. Australian Journal of Basic and Applied Sciences, 6(13): 454-462.
  • [16] Zhu, T., Luo, Y., Lin, Y., Li, Q., Yu, P., Zeng, M. (2010). Study of pervaporation for dehydration of caprolactam through blend NaAlg–poly(vinyl pyrrolidone) membranes on PAN supports. Separation and Purification Technology, 74(2):242–252.
  • [17] Ding, M., Xu, H., Chen, W., Yang, G., Kong, Q., Ng, D., Xie, Z. (2020). 2D laminar maleic acid-crosslinked MXene membrane with tunable nanochannels for efficient and stable pervaporation desalination. Journal of Membrane Science, 600: 117871.
There are 17 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Research Articles
Authors

Derya Ünlü 0000-0001-5240-5876

Publication Date June 15, 2020
Published in Issue Year 2020

Cite

APA Ünlü, D. (2020). Pervaporative Desalination of Water Using Hydroxypropyl methylcellulose / Polyvinylpyrrolidone Blend Membranes. Journal of Innovative Science and Engineering, 4(1), 35-43. https://doi.org/10.38088/jise.713852
AMA Ünlü D. Pervaporative Desalination of Water Using Hydroxypropyl methylcellulose / Polyvinylpyrrolidone Blend Membranes. JISE. June 2020;4(1):35-43. doi:10.38088/jise.713852
Chicago Ünlü, Derya. “Pervaporative Desalination of Water Using Hydroxypropyl Methylcellulose / Polyvinylpyrrolidone Blend Membranes”. Journal of Innovative Science and Engineering 4, no. 1 (June 2020): 35-43. https://doi.org/10.38088/jise.713852.
EndNote Ünlü D (June 1, 2020) Pervaporative Desalination of Water Using Hydroxypropyl methylcellulose / Polyvinylpyrrolidone Blend Membranes. Journal of Innovative Science and Engineering 4 1 35–43.
IEEE D. Ünlü, “Pervaporative Desalination of Water Using Hydroxypropyl methylcellulose / Polyvinylpyrrolidone Blend Membranes”, JISE, vol. 4, no. 1, pp. 35–43, 2020, doi: 10.38088/jise.713852.
ISNAD Ünlü, Derya. “Pervaporative Desalination of Water Using Hydroxypropyl Methylcellulose / Polyvinylpyrrolidone Blend Membranes”. Journal of Innovative Science and Engineering 4/1 (June 2020), 35-43. https://doi.org/10.38088/jise.713852.
JAMA Ünlü D. Pervaporative Desalination of Water Using Hydroxypropyl methylcellulose / Polyvinylpyrrolidone Blend Membranes. JISE. 2020;4:35–43.
MLA Ünlü, Derya. “Pervaporative Desalination of Water Using Hydroxypropyl Methylcellulose / Polyvinylpyrrolidone Blend Membranes”. Journal of Innovative Science and Engineering, vol. 4, no. 1, 2020, pp. 35-43, doi:10.38088/jise.713852.
Vancouver Ünlü D. Pervaporative Desalination of Water Using Hydroxypropyl methylcellulose / Polyvinylpyrrolidone Blend Membranes. JISE. 2020;4(1):35-43.


Creative Commons License

The works published in Journal of Innovative Science and Engineering (JISE) are licensed under a  Creative Commons Attribution-NonCommercial 4.0 International License.