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Usage of acetic acid for boric acid production from boron wastes

Yıl 2022, Cilt: 11 Sayı: 3, 819 - 825, 18.07.2022
https://doi.org/10.28948/ngumuh.1088309

Öz

Turkey's boric acid production has the highest production share among refined boron products. This production is takes place at the Bandırma (Balıkesir) and Emet (Kütahya) Boric Acid Plants of ETI Maden Operations. Concentrated ore (by physical processes) and high-grade wastes accumulated in waste ponds/dams are obtained from boron production plants. In this study, slime size (d80=52.70μm) wastes belonging to the Bigadiç field with 9-12% B2O3 (ulexite-colemanite) content have been evaluated. Due to the small size of feeding without the need for grinding, the sample was subjected to leaching of acetic acid at 60°C for 1 hour, at a mixing speed of 1500 rpm, at 7% solids. In addition to the recovery of 90% H3BO3 (at 4% acid concentration) after the leaching process, different compounds such as Na2O, and CaO were also obtained. Similar peaks were found in the FT-IR analyzes of boric acid and the product obtained. This study is an important output in terms of evaluating the % B2O3 content in the wastes of both this plant and other boron plants.

Kaynakça

  • V. Arslan and O. Bayat, “Kolemanit Cevherinden Oksalik Asit Liçi ile Borik Asit Eldesi (in Turkish), Production of Boric Acid From Colemanite Ore by Oxalic Acid Leaching,” J. Undergr. Resour. Altı Kaynakları Derg., no. 10, pp. 11–20, 2016, Accessed: Dec. 07, 2021. [Online]. Available: www.mtbilimsel.com.
  • BSR, “Bor Sektör Raporu/Boron Sector Report 2020,” Ankara, Turkey, 2020.
  • T. Guyaguler, “Türkiye bor potansiyeli,” in 4. Industrial Mineral Symposium, 2001, pp. 18–27.
  • S. G. Ozkan, “Comparison of Magnetic Separation and Flotation Results for Beneficiation of Emet Colemanite Ores,” Magn. Electr. Sep., vol. 10, no. 4, pp. 213–221, 2001, doi: 10.1155/2001/10257.
  • N. Acarkan, “Boron Products and Their Uses/Bor ürün çeşitleri ve kullanım alanları (in Turkish),” I. Uluslararası Bor Sempozyumu, pp. 1–5, 2002.
  • C. Bilal, “Kolemanitin Sülfürik Asit ile Reaksiyon Kinetiğinin İncelenmesi/The reaction kinetics of colemanite with sulfuric acid (in Turkish),” ITU, Istanbul, 2003.
  • C. Helvacı, “Turkish borate deposits : Geological setting, economic importance and boron policy/ Türkiye Borat Yatakları: Jeolojik Konumu, Ekonomik Önemi ve Bor Politikası (in Turkish),” in 5th Industrial Minerals Symp., 2004, pp. 11–27.
  • F. Göktepe, “Bigadiç bor atıklarının flotasyonla zenginleştirilebilirliğinin ön araştırması/Concentration Study of Bigadiç Boron Tailings by Flotation (in Turkish),” in 2nd International Boron Symposium, 2004, pp. 81–86.
  • E. Yoğurtcuoğlu and O. Dalgalı, “Evaluation of Bigadiç Colemanite and Ulexite Slurry Wastes by Heap Leach/Bigadiç kolemanit ve üleksit şlam atıklarının yığın liçi ile değerlendirilmesi (in Turkish),” in International Boron Symposium, 2019, pp. 102–106.
  • E. Yoğurtcuoğlu, “Bigadiç Bor Atıklarından Sitrik Asit ile Borik Asit Elde Edilmesi/The Production of Boric Acid with Citric Acid from Bigadic Bor Wastes (in Turkish),” in 1st Intarnational Conference on Environment, Technology and Management (ICETEM), 2019, pp. 1054–1060.
  • C. Ozmetin, M. M. Kocakerim, S. Yapıcı, and A. Yartaşı, “A Semiempirical Kinetic Model for Dissolution of Colemanite in Aqueous CH3COOH Solutions,” Ind. Eng. Chem. Res., vol. 35, no. 7, pp. 2355–2359, 1996.
  • G. Sertkaya and B. Bayat, “Kolemanit Atıklarından Biyoliç Yöntemi ile Borik Asit Eldesi/Production of Boric Acid From Colemanite Wastes by Bioleaching tailings,” Ç.U. Sci., vol. 17, no. 7, pp. 1–10, 2008.
  • C. Helvacı, “Borate deposits: An overview and future forecast with regard to mineral deposits,” J. Boron, vol. 2, no. 2, pp. 59–70, 2017, [Online]. Available: https://dergipark.org.tr/boron/issue/31236/302668.
  • Y. Erdoğan, A. Olgun, F. Özmal, and B. Zeybek, “Utilization of Boron Industry Wastes, Fly Ash, Bottom Ash and Alunite Mineral in Cement Production as an Additive Material,” 455-461, 2nd International Boron Symposium, 2004.
  • A. T. Baydır and Y. Erdoğan, “Dissolution Of The Rubidium From Eti Mine Kırka Boron Management Waste,” Afyon Kocatepe Univ. J. Sci. Eng., vol. 13, no. 2, pp. 13–20, 2013, doi: 10.5578/fmbd.6511.
  • B. Yaman and N. Çalış Açıkbaş, “Dry Sliding Behaviour of Boron Waste Reinforced Epoxy Matrix Composites,” J. Boron, vol. 3, no. 2, pp. 63–70, 2018, doi: 10.30728/boron.343608.
  • R. Boncukcuoǧlu, M. M. Kocakerim, E. Kocadaǧistan, and M. T. Yilmaz, “Recovery of boron of the sieve reject in the production of borax,” Resour. Conserv. Recycl., vol. 37, no. 2, pp. 147–157, 2003, doi: 10.1016/S0921-3449(02)00072-1.
  • I. Y. Elbeyli, “Production of crystalline boric acid and sodium citrate from borax decahydrate,” Hydrometallurgy, vol. 158, pp. 19–26, 2015, doi: 10.1016/j.hydromet.2015.09.022.
  • H. Tüzün, S. Ün, and Ş. Buğdaycı, “Konsantre ve Rafine Bor Ürünler,” in International Symposium on Boron, 2019, pp. 63–70.
  • C. Helvacı, “Türkiye Borat Yatakları Jeolojik Konumu, Ekonomik Önemi ve Bor Politikası,” Balıkesir Üniversitesi Fen Bilim. Enstitüsü Derg., vol. 5, no. 1, pp. 4–41, 2003.
  • C. Helvacı, “Bor madenciliğinde işletme, zenginleştirme ve pazarlama sorunları, Mining, Dressing and Marketing problems of Borate Minerals (in Turkish),” in 3rd International Boron Symposium, 2006, pp. 559–571.
  • Ö. Gülsoy, L. Ergün, M. Can, A. Mergen, T. Ergül, and T. Aydın, “Bigadiç bor konsantratörü için alternatif zenginleştime yöntemi (in Turkish),” in 3. International Boron Symposium, 2006, pp. 307–313.
  • C. Helvacı, “Bor Yataklarini İçeren Neojen Havzalarinin Jeoloji̇ Özelli̇kleri̇: Yataklarin Genel Değerlendi̇rmesi̇ ve Gelecek Öngörüsü,Türki̇ye,” Maden Tetk. ve Aram. Derg., vol. 0, no. 151, 2015, doi: 10.19076/mta.75175.
  • Boron as the Rising Value of Turkey https://www.etimaden.gov.tr/en/boron-in-turkey Accessed 18.01.2022
  • M. Özdemir and N. U. Öztürk, “Utilization of clay wastes containing boron as cement additives,” Cem. Concr. Res., vol. 33, no. 10, pp. 1659–1661, 2003, doi: 10.1016/S0008-8846(03)00138-8.
  • E. Yoğurtcuoğlu, “Üleksit-Kolemanit İçeren Bor Şlam Atıklarından Borun Geri Kazanımı/Recovery of Boron from Boron Slurry Wastes Containing Ulexite-Colemanit (in Turkish),” in International Turkic World Congress on Science and Engineering, 2019, pp. 1262–1267.
  • T. Batar, S. Bayça, Ö. Solak, E. Sayın, E. Can, and B. Kahraman, “Effects of boron ore and its tailings to the ceramic wall tile structure (in Turkish).,” in 6th International Industrial Minerals Symposium, 2007, pp. 328–333.
  • E. Sayın, T. Batar, Ö. Solak, A. Yamık, and M. B. Tufan, “Use of tincal ore and boron tailings in ceramic paste and water insulating mortar (in Turkish),” in 6th International Industrial Minerals Symposium, 2007, pp. 428–437.
  • İ. Bentli, O. Özdemir, M. S. Çelik, and N. Ediz, “Bor Atıkları ve Değerlendirilme Stratejileri Boron Tailings and Evaluation Strategies,” in The First International Boron Symposium, 2001, pp. 250–258.
  • G. Sertkaya, “Kolemanit atıklardan biyoliç yöntemi ile borik asit eldesi/Production of boric acid from colemanite wastes by bioleaching tailings (in Turkish),” Çukurova University, 2007.
  • N. Ediz and H. Özdag, “Etibor A.Ş. Kırka Boraks İsletmesi Tinkal Cevheri ve Atıklarının Doğrudan Zenginleştrilmesi/Direct Processing of Tincal Ores and the Wastes of the Etibor A.S. Kırka Borax Mine,” Turkish J. Eng. Env. Sci., vol. 26, pp. 107–116, 2002.
  • A. Ekmekyapar, N. Demirkiran, and A. Künkül, “Dissolution kinetics of ulexite in acetic acid solutions,” Chem. Eng. Res. Des., vol. 86, no. 9, pp. 1011–1016, 2008, doi: 10.1016/j.cherd.2008.04.005.
  • S. U. Bayca, “Recovery of Boric Acid From Colemanite Waste by Sulfuric Acid Leaching and Crystallization,” pp. 793–804, 2007.
  • A. N. Bulutcu, C. O. Ertekin, and M. B. Kuskay Celikoyan, “Impurity control in the production of boric acid from colemanite in the presence of propionic acid,” Chem. Eng. Process. Process Intensif., vol. 47, no. 12, pp. 2270–2274, 2008, doi: 10.1016/j.cep.2007.12.012.
  • B. Kuşkay Çelikoyan and A. N. Bulutcu, “Kolemanitten yeni bir yöntemle borik asit üretim prosesinin geliştirilmesi/Development of a new method for the boric acid production process from colemanite ore (in Turkish),” İTU J., vol. 9, no. 2, pp. 15–26, 2010.
  • B. Kuskay and A. N. Bulutcu, “Design parameters of boric acid production process from colemanite ore in the presence of propionic acid,” Chem. Eng. Process. Process Intensif., vol. 50, no. 4, pp. 377–383, 2011, doi: 10.1016/j.cep.2011.02.013.
  • O. Laçin, B. Dönmez, and F. Demir, “Dissolution kinetics of natural magnesite in acetic acid solutions,” Int. J. Miner. Process., vol. 75, no. 1–2, pp. 91–99, 2005, doi: 10.1016/j.minpro.2004.05.002.
  • B. Dönmez, F. Demir, and O. Laçin, “Leaching kinetics of calcined magnesite in acetic acid solutions,” J. Ind. Eng. Chem., vol. 15, no. 6, pp. 865–869, 2009, doi: 10.1016/j.jiec.2009.09.014.
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Bor atıklarından borik asit üretiminde asetik asidin kullanımı

Yıl 2022, Cilt: 11 Sayı: 3, 819 - 825, 18.07.2022
https://doi.org/10.28948/ngumuh.1088309

Öz

Türkiye'nin borik asit üretimi rafine bor ürünleri arasında en yüksek üretim payına sahiptir. Söz konusu bu üretim ETİ Maden İşletmelerinin Bandırma (Balıkesir) ve Emet (Kütahya) Borik Asit Tesislerinden üretilmektedir. Bor üretim tesislerinden konsantre cevher (fiziksel işlemlerle) ve atık havuzlarında/barajlarda biriktirilen yüksek tenörlü atıklar elde edilmektedir. Bu çalışmada, Bigadiç sahasına ait %9-12 B2O3 (üleksit-kolemanit) içeriğine sahip şlam boyutundaki (d90=81.94μm) atıklar değerlendirilmiştir. Numune, öğütülmeye ihtiyaç duyulmadan küçük besleme boyutundan dolayı 60°C'de 1 saat, 1500 rpm karıştırma hızında, %7 katı oranında asetik asit liç işlemine tabi tutulmuştur. Liç işlemi sonrasında %90 H3BO3 (%4 asit konsantrasyonunda) veriminin yanı sıra Na2O ve CaO gibi farklı bileşikler de elde edilmiştir. Borik asit ve elde edilen ürünün FT-IR analizlerinde benzer pikler bulunmuştur. Bu çalışma, hem bu tesisin hem de diğer bor tesislerinin atıklarındaki % B2O3 içeriğinin değerlendirilmesi açısından önemli bir çıktıdır.

Kaynakça

  • V. Arslan and O. Bayat, “Kolemanit Cevherinden Oksalik Asit Liçi ile Borik Asit Eldesi (in Turkish), Production of Boric Acid From Colemanite Ore by Oxalic Acid Leaching,” J. Undergr. Resour. Altı Kaynakları Derg., no. 10, pp. 11–20, 2016, Accessed: Dec. 07, 2021. [Online]. Available: www.mtbilimsel.com.
  • BSR, “Bor Sektör Raporu/Boron Sector Report 2020,” Ankara, Turkey, 2020.
  • T. Guyaguler, “Türkiye bor potansiyeli,” in 4. Industrial Mineral Symposium, 2001, pp. 18–27.
  • S. G. Ozkan, “Comparison of Magnetic Separation and Flotation Results for Beneficiation of Emet Colemanite Ores,” Magn. Electr. Sep., vol. 10, no. 4, pp. 213–221, 2001, doi: 10.1155/2001/10257.
  • N. Acarkan, “Boron Products and Their Uses/Bor ürün çeşitleri ve kullanım alanları (in Turkish),” I. Uluslararası Bor Sempozyumu, pp. 1–5, 2002.
  • C. Bilal, “Kolemanitin Sülfürik Asit ile Reaksiyon Kinetiğinin İncelenmesi/The reaction kinetics of colemanite with sulfuric acid (in Turkish),” ITU, Istanbul, 2003.
  • C. Helvacı, “Turkish borate deposits : Geological setting, economic importance and boron policy/ Türkiye Borat Yatakları: Jeolojik Konumu, Ekonomik Önemi ve Bor Politikası (in Turkish),” in 5th Industrial Minerals Symp., 2004, pp. 11–27.
  • F. Göktepe, “Bigadiç bor atıklarının flotasyonla zenginleştirilebilirliğinin ön araştırması/Concentration Study of Bigadiç Boron Tailings by Flotation (in Turkish),” in 2nd International Boron Symposium, 2004, pp. 81–86.
  • E. Yoğurtcuoğlu and O. Dalgalı, “Evaluation of Bigadiç Colemanite and Ulexite Slurry Wastes by Heap Leach/Bigadiç kolemanit ve üleksit şlam atıklarının yığın liçi ile değerlendirilmesi (in Turkish),” in International Boron Symposium, 2019, pp. 102–106.
  • E. Yoğurtcuoğlu, “Bigadiç Bor Atıklarından Sitrik Asit ile Borik Asit Elde Edilmesi/The Production of Boric Acid with Citric Acid from Bigadic Bor Wastes (in Turkish),” in 1st Intarnational Conference on Environment, Technology and Management (ICETEM), 2019, pp. 1054–1060.
  • C. Ozmetin, M. M. Kocakerim, S. Yapıcı, and A. Yartaşı, “A Semiempirical Kinetic Model for Dissolution of Colemanite in Aqueous CH3COOH Solutions,” Ind. Eng. Chem. Res., vol. 35, no. 7, pp. 2355–2359, 1996.
  • G. Sertkaya and B. Bayat, “Kolemanit Atıklarından Biyoliç Yöntemi ile Borik Asit Eldesi/Production of Boric Acid From Colemanite Wastes by Bioleaching tailings,” Ç.U. Sci., vol. 17, no. 7, pp. 1–10, 2008.
  • C. Helvacı, “Borate deposits: An overview and future forecast with regard to mineral deposits,” J. Boron, vol. 2, no. 2, pp. 59–70, 2017, [Online]. Available: https://dergipark.org.tr/boron/issue/31236/302668.
  • Y. Erdoğan, A. Olgun, F. Özmal, and B. Zeybek, “Utilization of Boron Industry Wastes, Fly Ash, Bottom Ash and Alunite Mineral in Cement Production as an Additive Material,” 455-461, 2nd International Boron Symposium, 2004.
  • A. T. Baydır and Y. Erdoğan, “Dissolution Of The Rubidium From Eti Mine Kırka Boron Management Waste,” Afyon Kocatepe Univ. J. Sci. Eng., vol. 13, no. 2, pp. 13–20, 2013, doi: 10.5578/fmbd.6511.
  • B. Yaman and N. Çalış Açıkbaş, “Dry Sliding Behaviour of Boron Waste Reinforced Epoxy Matrix Composites,” J. Boron, vol. 3, no. 2, pp. 63–70, 2018, doi: 10.30728/boron.343608.
  • R. Boncukcuoǧlu, M. M. Kocakerim, E. Kocadaǧistan, and M. T. Yilmaz, “Recovery of boron of the sieve reject in the production of borax,” Resour. Conserv. Recycl., vol. 37, no. 2, pp. 147–157, 2003, doi: 10.1016/S0921-3449(02)00072-1.
  • I. Y. Elbeyli, “Production of crystalline boric acid and sodium citrate from borax decahydrate,” Hydrometallurgy, vol. 158, pp. 19–26, 2015, doi: 10.1016/j.hydromet.2015.09.022.
  • H. Tüzün, S. Ün, and Ş. Buğdaycı, “Konsantre ve Rafine Bor Ürünler,” in International Symposium on Boron, 2019, pp. 63–70.
  • C. Helvacı, “Türkiye Borat Yatakları Jeolojik Konumu, Ekonomik Önemi ve Bor Politikası,” Balıkesir Üniversitesi Fen Bilim. Enstitüsü Derg., vol. 5, no. 1, pp. 4–41, 2003.
  • C. Helvacı, “Bor madenciliğinde işletme, zenginleştirme ve pazarlama sorunları, Mining, Dressing and Marketing problems of Borate Minerals (in Turkish),” in 3rd International Boron Symposium, 2006, pp. 559–571.
  • Ö. Gülsoy, L. Ergün, M. Can, A. Mergen, T. Ergül, and T. Aydın, “Bigadiç bor konsantratörü için alternatif zenginleştime yöntemi (in Turkish),” in 3. International Boron Symposium, 2006, pp. 307–313.
  • C. Helvacı, “Bor Yataklarini İçeren Neojen Havzalarinin Jeoloji̇ Özelli̇kleri̇: Yataklarin Genel Değerlendi̇rmesi̇ ve Gelecek Öngörüsü,Türki̇ye,” Maden Tetk. ve Aram. Derg., vol. 0, no. 151, 2015, doi: 10.19076/mta.75175.
  • Boron as the Rising Value of Turkey https://www.etimaden.gov.tr/en/boron-in-turkey Accessed 18.01.2022
  • M. Özdemir and N. U. Öztürk, “Utilization of clay wastes containing boron as cement additives,” Cem. Concr. Res., vol. 33, no. 10, pp. 1659–1661, 2003, doi: 10.1016/S0008-8846(03)00138-8.
  • E. Yoğurtcuoğlu, “Üleksit-Kolemanit İçeren Bor Şlam Atıklarından Borun Geri Kazanımı/Recovery of Boron from Boron Slurry Wastes Containing Ulexite-Colemanit (in Turkish),” in International Turkic World Congress on Science and Engineering, 2019, pp. 1262–1267.
  • T. Batar, S. Bayça, Ö. Solak, E. Sayın, E. Can, and B. Kahraman, “Effects of boron ore and its tailings to the ceramic wall tile structure (in Turkish).,” in 6th International Industrial Minerals Symposium, 2007, pp. 328–333.
  • E. Sayın, T. Batar, Ö. Solak, A. Yamık, and M. B. Tufan, “Use of tincal ore and boron tailings in ceramic paste and water insulating mortar (in Turkish),” in 6th International Industrial Minerals Symposium, 2007, pp. 428–437.
  • İ. Bentli, O. Özdemir, M. S. Çelik, and N. Ediz, “Bor Atıkları ve Değerlendirilme Stratejileri Boron Tailings and Evaluation Strategies,” in The First International Boron Symposium, 2001, pp. 250–258.
  • G. Sertkaya, “Kolemanit atıklardan biyoliç yöntemi ile borik asit eldesi/Production of boric acid from colemanite wastes by bioleaching tailings (in Turkish),” Çukurova University, 2007.
  • N. Ediz and H. Özdag, “Etibor A.Ş. Kırka Boraks İsletmesi Tinkal Cevheri ve Atıklarının Doğrudan Zenginleştrilmesi/Direct Processing of Tincal Ores and the Wastes of the Etibor A.S. Kırka Borax Mine,” Turkish J. Eng. Env. Sci., vol. 26, pp. 107–116, 2002.
  • A. Ekmekyapar, N. Demirkiran, and A. Künkül, “Dissolution kinetics of ulexite in acetic acid solutions,” Chem. Eng. Res. Des., vol. 86, no. 9, pp. 1011–1016, 2008, doi: 10.1016/j.cherd.2008.04.005.
  • S. U. Bayca, “Recovery of Boric Acid From Colemanite Waste by Sulfuric Acid Leaching and Crystallization,” pp. 793–804, 2007.
  • A. N. Bulutcu, C. O. Ertekin, and M. B. Kuskay Celikoyan, “Impurity control in the production of boric acid from colemanite in the presence of propionic acid,” Chem. Eng. Process. Process Intensif., vol. 47, no. 12, pp. 2270–2274, 2008, doi: 10.1016/j.cep.2007.12.012.
  • B. Kuşkay Çelikoyan and A. N. Bulutcu, “Kolemanitten yeni bir yöntemle borik asit üretim prosesinin geliştirilmesi/Development of a new method for the boric acid production process from colemanite ore (in Turkish),” İTU J., vol. 9, no. 2, pp. 15–26, 2010.
  • B. Kuskay and A. N. Bulutcu, “Design parameters of boric acid production process from colemanite ore in the presence of propionic acid,” Chem. Eng. Process. Process Intensif., vol. 50, no. 4, pp. 377–383, 2011, doi: 10.1016/j.cep.2011.02.013.
  • O. Laçin, B. Dönmez, and F. Demir, “Dissolution kinetics of natural magnesite in acetic acid solutions,” Int. J. Miner. Process., vol. 75, no. 1–2, pp. 91–99, 2005, doi: 10.1016/j.minpro.2004.05.002.
  • B. Dönmez, F. Demir, and O. Laçin, “Leaching kinetics of calcined magnesite in acetic acid solutions,” J. Ind. Eng. Chem., vol. 15, no. 6, pp. 865–869, 2009, doi: 10.1016/j.jiec.2009.09.014.
  • K. Bay, “Kolemanitten Zayıf Asitlerle Borik Asit Üretimi,” İstanbul Technical University, 2002.
  • F. G. Cirujano and F. X. Llabrés I Xamena, “Tuning the Catalytic Properties of UiO-66 Metal-Organic Frameworks: From Lewis to Defect-Induced Brønsted Acidity,” J. Phys. Chem. Lett., vol. 11, no. 12, pp. 4879–4890, 2020, doi: 10.1021/acs.jpclett.0c00984.
  • J. . Pironon, M. Pelletier, P. De Donato, and R. Mosser-Ruck, “ Characterization of smectite and illite by FTIR spectroscopy of interlayer NH 4 + cations ,” Clay Miner., vol. 38, no. 2, pp. 201–211, 2003, doi: 10.1180/0009855033820089.
  • B. B. Zviagina, V. A. Drits, and O. V. Dorzhieva, “Distinguishing features and identification criteria for K-dioctahedral 1M micas (Illite-aluminoceladonite and illite-glauconite-celadonite series) from middle-infrared spectroscopy data,” Minerals, vol. 10, no. 2, 2020, doi: 10.3390/min10020153.
  • C. M. Muller, B. Pejcic, L. steban, C. D. Piane, M. Raven, and B. Mizaikoff, “Infrared Attenuated Total ReflectanceSpectroscopy An Innovative Strategy forAnalyzing Mineral Components inEnergy Relevant Systems.pdf.” 2014, DOI: 10.1038/srep06764.
  • E. Aliyari, M. Alvand, and F. Shemirani, “Modified surface-active ionic liquid-coated magnetic graphene oxide as a new magnetic solid phase extraction sorbent for preconcentration of trace nickel,” RSC Adv., vol. 6, no. 69, pp. 64193–64202, 2016, doi: 10.1039/c6ra04163a.
  • A. Budak and M. Gönen, “Extraction of boric acid from colemanite mineral by supercritical carbon dioxide,” J. Supercrit. Fluids, vol. 92, pp. 183–189, 2014, doi: 10.1016/j.supflu.2014.05.016.
  • G. G. Hacıosmanoğlu, S. Genç, and Z. S. Can, “Efficient removal of methyl orange from aqueous solutions using ulexite,” Environ. Technol. Innov., vol. 22, p. 101466, 2021, doi: 10.1016/j.eti.2021.101466.
  • Y. Lu, J. Drelich, and J. D. Miller, “Oleate adsorption at an apatite surface studied by ex-situ FTIR internal reflection spectroscopy,” J. Colloid Interface Sci., vol. 202, no. 2, pp. 462–476, 1998, doi: 10.1006/jcis.1998.5466.
  • R. Ragupathi Raja Kannan, R. Arumugam, and P. Anantharaman, “Fourier Transform Infrared Spectroscopy Analysis of Seagrass Polyphenols,” Curr. Bioact. Compd., vol. 7, no. 2, pp. 118–125, 2011, doi: 10.2174/157340711796011142.
  • G. F. Mohamed, M. S. Shaheen, S. K. H. Khalil, A. M. S. Hussein, and M. M. Kamil, “Application of FT-IR Spectroscopy for Rapid and Simultaneous Quality Determination of Some Fruit Products,” Nat. Sci., vol. 9, no. 11, pp. 21–31, 2011.
  • F. Demir, O. Laçin, and B. Dönmez, “Leaching Kinetics of Calcined Magnesite in Citric Acid Solutions,” Ind. Eng. Chem. Res., vol. 45, no. 4, pp. 1307–1311, 2006, doi: 10.1016/j.jiec.2009.09.014.
  • K. Song, S. Park, W. Kim, C.W. Jeon, J.W. Ahn, Effects of experimental parameters on the extraction of silica and carbonation of blast furnace slag at atmospheric pressure in low-concentration acetic acid, Metals (Basel). 7 (2017). https://doi.org/10.3390/met7060199.
  • B. Terry, The acid decomposition of silicate minerals part II. Hydrometallurgical applications, Hydrometallurgy. 10 (1983) 151–171. https://doi.org/10.1016/0304-386X(83)90003-8.
Toplam 52 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik, Kimya Mühendisliği, Malzeme Üretim Teknolojileri
Bölüm Malzeme ve Metalürji Mühendisliği
Yazarlar

Emine Yoğurtcuoğlu 0000-0002-9961-8809

Yayımlanma Tarihi 18 Temmuz 2022
Gönderilme Tarihi 15 Mart 2022
Kabul Tarihi 26 Nisan 2022
Yayımlandığı Sayı Yıl 2022 Cilt: 11 Sayı: 3

Kaynak Göster

APA Yoğurtcuoğlu, E. (2022). Usage of acetic acid for boric acid production from boron wastes. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 11(3), 819-825. https://doi.org/10.28948/ngumuh.1088309
AMA Yoğurtcuoğlu E. Usage of acetic acid for boric acid production from boron wastes. NÖHÜ Müh. Bilim. Derg. Temmuz 2022;11(3):819-825. doi:10.28948/ngumuh.1088309
Chicago Yoğurtcuoğlu, Emine. “Usage of Acetic Acid for Boric Acid Production from Boron Wastes”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 11, sy. 3 (Temmuz 2022): 819-25. https://doi.org/10.28948/ngumuh.1088309.
EndNote Yoğurtcuoğlu E (01 Temmuz 2022) Usage of acetic acid for boric acid production from boron wastes. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 11 3 819–825.
IEEE E. Yoğurtcuoğlu, “Usage of acetic acid for boric acid production from boron wastes”, NÖHÜ Müh. Bilim. Derg., c. 11, sy. 3, ss. 819–825, 2022, doi: 10.28948/ngumuh.1088309.
ISNAD Yoğurtcuoğlu, Emine. “Usage of Acetic Acid for Boric Acid Production from Boron Wastes”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 11/3 (Temmuz 2022), 819-825. https://doi.org/10.28948/ngumuh.1088309.
JAMA Yoğurtcuoğlu E. Usage of acetic acid for boric acid production from boron wastes. NÖHÜ Müh. Bilim. Derg. 2022;11:819–825.
MLA Yoğurtcuoğlu, Emine. “Usage of Acetic Acid for Boric Acid Production from Boron Wastes”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, c. 11, sy. 3, 2022, ss. 819-25, doi:10.28948/ngumuh.1088309.
Vancouver Yoğurtcuoğlu E. Usage of acetic acid for boric acid production from boron wastes. NÖHÜ Müh. Bilim. Derg. 2022;11(3):819-25.

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