Research Article
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Production of Chemically and Microwave Activated Hazelnut Husk As An Adsorbent for Dye Contaminated Wastewaters

Year 2022, , 46 - 60, 08.06.2022

Nilüfer Ülgüdür , Pınar Sevim Elibol , Emine Malkoç

https://doi.org/10.38088/jise.904809

Abstract

Adsorption has traditionally been evaluated as an economical and easily applicable process for treating certain wastewaters, such as ones including dyes and heavy metals. Even though adsorbent materials specifically produced for the purpose of wastewater treatment commercially exist, the production cost may create an economic burden on wastewater treatment processes. Agricultural wastes can be valorized as adsorbents in adsorption processes. The adsorption capacity of these wastes can be improved via pre-treatment methods such as chemical application and microwave irradiation. This study investigated the potential applicability of hazelnut husk as an adsorbent for methylene blue (MB) dye. To this purpose, the husk was activated by sequential chemical or water and microwave applications. Structural analysis on the produced adsorbent was performed by Fourier transform infrared spectrophotometry (FTIR) and field emission scanning electron microscopy (FE-SEM). Isotherm (Langmuir, Freundlich, Temkin and Harkins-Jura isotherms) and kinetic (pseudo-first-order, pseudo-second-order, Elovich and intraparticle diffusion kinetic models) behaviours of adsorption were also evaluated. The results indicated that MB could be removed by 92-94% considering all adsorbents produced. Further isotherm and kinetic studies revealed that MB adsorption was both physically and chemically induced, and the reaction followed the pseudo-second-order kinetic model (R2>0.99).

Keywords

Adsorption Dye Waste Microwave Hazelnut Husk Absorbent

Supporting Institution

Duzce University Scientific Research Projects Coordination

Project Number

DUBAP- 2020.06.02.1072

References

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Year 2022, , 46 - 60, 08.06.2022

Nilüfer Ülgüdür , Pınar Sevim Elibol , Emine Malkoç

https://doi.org/10.38088/jise.904809

Abstract

Project Number

DUBAP- 2020.06.02.1072

References

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  • [17] S. Sivrikaya, S. Albayrak, M. Imamoglu, A. Gundogdu, C. Duran, H. Yildiz, Dehydrated hazelnut husk carbon: A novel sorbent for removal of Ni(II) ions from aqueous solution. Desalination and Water Treatment, 50 (2012) 2–13. https://doi.org/10.1080/19443994.2012.708234.
  • [18] M. Imamoglu, H. Şahin, Ş. Aydın, F. Tosunoğlu, H. Yılmaz, S. Z. Yıldız, Investigation of Pb(II) adsorption on a novel activated carbon prepared from hazelnut husk by K2CO3 activation. Desalination and Water Treatment, 57 (2016) 4587–4596. https://doi.org/10.1080/19443994.2014.995135.
  • [19] H. Deng, G. Li, H. Yang, J. Tang, J. Tang, Preparation of activated carbons from cotton stalk by microwave assisted KOH and K2CO3 activation. Chemical Engineering Journal, 163 (2010) 373–381. https://doi.org/10.1016/j.cej.2010.08.019.
  • [20] T. H. Tran, A. H. Le, T. H. Pham, D. T. Nguyen, S. W. Chang, W. J. Chung, D. D. Nguyen, Adsorption isotherms and kinetic modeling of methylene blue dye onto a carbonaceous hydrochar adsorbent derived from coffee husk waste. Science of the Total Environment, 725 (2020) 138325. https://doi.org/10.1016/j.scitotenv.2020.138325.
  • [21] Y. Chen, Y. Zhu, Z. Wang, Y. Li, L. Wang, L. Ding, X. Gao, Y. Ma, Y. Guo, Application studies of activated carbon derived from rice husks produced by chemical-thermal process - A review. Advances in Colloid and Interface Science, 163 (2011) 39–52. https://doi.org/10.1016/j.cis.2011.01.006.
  • [22] Ahmadpour D. D. Do, The preparation of activated carbon from macadamia nutshell by chemical activation. Carbon, 35 (1997) 1723–1732.
  • [23] D. Prahas, Y. Kartika, N. Indraswati, S. Ismadji, Activated carbon from jackfruit peel waste by H3PO4 chemical activation: Pore structure and surface chemistry characterization. Chemical Engineering Journal, 140 (2008) 32–42. https://doi.org/10.1016/j.cej.2007.08.032.
  • [24] S. Al-Asheh, F. Banat, L. Abu-Aitah, The removal of methylene blue dye from aqueous solutions using activated and non-activated bentonites. Adsorption Science and Technology, 21 (2003) 451–462. https://doi.org/10.1260/026361703769645780.
  • [25] O. S. Bello, K. A. Adegoke, A. A. Olaniyan, H. Abdulazeez, Dye adsorption using biomass wastes and natural adsorbents: Overview and future prospects. Desalination and Water Treatment, 53 (2015) 1292–1315. https://doi.org/10.1080/19443994.2013.862028.
  • [26] W. Jiang, L. Zhang, X. Guo, M. Yang, Y. Lu, Y. Wang, Y. Zheng, G. Wei, Adsorption of cationic dye from water using an iron oxide/activated carbon magnetic composites prepared from sugarcane bagasse by microwave method. Environmental Technology (United Kingdom), (2019) 1–14. https://doi.org/10.1080/09593330.2019.1627425.
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  • [29] Kahoul, N. Bougdah, F. Djazi, C. Djilani, P. Magri, M. S. Medjram, Removal of methylene blue by adsorption onto activated carbons produced from agricultural wastes by microwave induced KOH activation. Chemistry and Chemical Technology, 13 (2019) 365–371. https://doi.org/10.23939/chcht13.03.365.
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Details

Primary Language English
Subjects Engineering
Journal Section Research Articles
Authors

Nilüfer Ülgüdür 0000-0003-3410-0598

Pınar Sevim Elibol 0000-0001-7758-4583

Emine Malkoç 0000-0002-9030-7684

Project Number DUBAP- 2020.06.02.1072
Publication Date June 8, 2022
Published in Issue Year 2022

Cite

APA Ülgüdür, N., Sevim Elibol, P., & Malkoç, E. (2022). Production of Chemically and Microwave Activated Hazelnut Husk As An Adsorbent for Dye Contaminated Wastewaters. Journal of Innovative Science and Engineering, 6(1), 46-60. https://doi.org/10.38088/jise.904809
AMA Ülgüdür N, Sevim Elibol P, Malkoç E. Production of Chemically and Microwave Activated Hazelnut Husk As An Adsorbent for Dye Contaminated Wastewaters. JISE. June 2022;6(1):46-60. doi:10.38088/jise.904809
Chicago Ülgüdür, Nilüfer, Pınar Sevim Elibol, and Emine Malkoç. “Production of Chemically and Microwave Activated Hazelnut Husk As An Adsorbent for Dye Contaminated Wastewaters”. Journal of Innovative Science and Engineering 6, no. 1 (June 2022): 46-60. https://doi.org/10.38088/jise.904809.
EndNote Ülgüdür N, Sevim Elibol P, Malkoç E (June 1, 2022) Production of Chemically and Microwave Activated Hazelnut Husk As An Adsorbent for Dye Contaminated Wastewaters. Journal of Innovative Science and Engineering 6 1 46–60.
IEEE N. Ülgüdür, P. Sevim Elibol, and E. Malkoç, “Production of Chemically and Microwave Activated Hazelnut Husk As An Adsorbent for Dye Contaminated Wastewaters”, JISE, vol. 6, no. 1, pp. 46–60, 2022, doi: 10.38088/jise.904809.
ISNAD Ülgüdür, Nilüfer et al. “Production of Chemically and Microwave Activated Hazelnut Husk As An Adsorbent for Dye Contaminated Wastewaters”. Journal of Innovative Science and Engineering 6/1 (June 2022), 46-60. https://doi.org/10.38088/jise.904809.
JAMA Ülgüdür N, Sevim Elibol P, Malkoç E. Production of Chemically and Microwave Activated Hazelnut Husk As An Adsorbent for Dye Contaminated Wastewaters. JISE. 2022;6:46–60.
MLA Ülgüdür, Nilüfer et al. “Production of Chemically and Microwave Activated Hazelnut Husk As An Adsorbent for Dye Contaminated Wastewaters”. Journal of Innovative Science and Engineering, vol. 6, no. 1, 2022, pp. 46-60, doi:10.38088/jise.904809.
Vancouver Ülgüdür N, Sevim Elibol P, Malkoç E. Production of Chemically and Microwave Activated Hazelnut Husk As An Adsorbent for Dye Contaminated Wastewaters. JISE. 2022;6(1):46-60.


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