DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES

Ömer Faruk Ünsal; Yasin Altın; Ayşe Bedeloğlu

doi:10.17482/uumfd.730521

Research Article

DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES

Year 2020, Volume: 25 Issue: 2, 861 - 874, 31.08.2020

Ömer Faruk Ünsal Yasin Altın Ayşe Bedeloğlu

https://doi.org/10.17482/uumfd.730521

Cited By: 3

Abstract

In recent years, carbon nanotubes (CNTs) have emerged as materials that are often used in the preparation of polymer nanocomposites with conductive or advanced dielectric properties due to their unique properties including high temperature and electrical conductivity, which allows the production of very light and robust materials with a very high length-to-diameter ratio. However, during the preparation of polymeric nanocomposites with these materials, some problems are encountered. One of the major problems is that after preparing these conductive
materials or adding them into the polymer, they tend to aggregate, forming agglomerate, due to their conductive structures. Therefore, in this study, firstly, multi-walled carbon nanotubes (MWCNTs) were functionalized with conductive form of polyaniline (PANI) and subsequently, the poly (dimethyl siloxane) (PDMS) polymer nanocomposite films with different concentrations of functionalized multi-walled carbon nanotubes were prepared. Then, the structural, morphological, electrical and dielectric properties of the films were characterized. As a result, with the addition of only 1.5% PANI-CNT, the dielectric constant of PDMS was increased by 47-fold at 1 Hz. The dielectric films like presented here can be used in capacitors, flexible electronics, dielectric elastomers and artificial muscle applications.

Keywords

Carbon Nanotubes (CNTs), Conductive Polymer, Dielectric, Polyaniline (PANI), Polymer Nanocomposite, poly(dimethyl siloxane) (PDMS)

Project Number

2015-01-008

References

1. Bai, Y., Z.-Y. Cheng, V. Bharti, H. Xu and Q. Zhang (2000). "High-dielectric-constant ceramic-powder polymer composites." Applied Physics Letters 76(25): 3804-3806. https://doi.org/10.1063/1.126787
2. Bodas, D. and C. Khan-Malek (2006). "Formation of more stable hydrophilic surfaces of PDMS by plasma and chemical treatments." Microelectronic engineering 83(4-9): 1277-1279. https://doi.org/10.1016/j.mee.2006.01.195
3. Brochu, P. and Q. Pei (2010). "Advances in dielectric elastomers for actuators and artificial muscles." Macromolecular rapid communications 31(1): 10-36. https://doi.org/10.1002/marc.200900425
4. Brosseau, C., P. Quéffélec and P. Talbot (2001). "Microwave characterization of filled polymers." Journal of Applied Physics 89(8): 4532-4540. https://doi.org/10.1063/1.1343521
5. Carpi, F. and D. D. Rossi (2005). "Improvement of electromechanical actuating performances of a silicone dielectric elastomer by dispersion of titanium dioxide powder." IEEE Transactions on Dielectrics and Electrical Insulation 12(4): 835-843. DOI: 10.1109/TDEI.2005.1511110
6. Chen, G. H., D. J. Wu, W. G. Weng and W. L. Yan (2001). "Preparation of polymer/graphite conducting nanocomposite by intercalation polymerization." Journal of Applied Polymer Science 82(10): 2506-2513. https://doi.org/10.1002/app.2101
7. Dang, Z.-M., J.-K. Yuan, J.-W. Zha, T. Zhou, S.-T. Li and G.-H. Hu (2012). "Fundamentals, processes and applications of high-permittivity polymer–matrix composites." Progress in Materials Science 57(4): 660-723. https://doi.org/10.1016/j.pmatsci.2011.08.001
8. Dang, Z. M., Y. H. Lin and C. W. Nan (2003). "Novel ferroelectric polymer composites with high dielectric constants." Advanced Materials 15(19): 1625-1629. https://doi.org/10.1002/adma.200304911
9. Dang, Z. M., L. Wang, Y. Yin, Q. Zhang and Q. Q. Lei (2007). "Giant dielectric permittivities in functionalized carbon‐nanotube/electroactive‐polymer nanocomposites." Advanced Materials 19(6): 852-857. DOI: 10.1002/adma.200600703
10. Fan, P., L. Wang, S. Jia, F. Chen, J. Yang and M. Zhong (2017). "Encapsulated graphenes through ultrasonically initiated in situ polymerization: A route to high dielectric permittivity, low loss materials with low percolation threshold." Journal of Applied Polymer Science 134(12). https://doi.org/10.1002/app.44628
11. Huang, C. and Q. Zhang (2004). "Enhanced dielectric and electromechanical responses in high dielectric constant all‐polymer percolative composites." Advanced Functional Materials 14(5): 501-506. https://doi.org/10.1002/adfm.200305021
12. Huang, C., Q. Zhang, J. Y. Li and M. Rabeony (2005). "Colossal dielectric and electromechanical responses in self-assembled polymeric nanocomposites." Applied Physics Letters 87(18): 182901. DOI:10.1063/1.2105997
13. Huang, C., Q. Zhang and J. Su (2003). "High-dielectric-constant all-polymer percolative composites." Applied Physics Letters 82(20): 3502-3504. https://doi.org/10.1063/1.1575505
14. Javadi, A., Y. Xiao, W. Xu and S. Gong (2012). "Chemically modified graphene/P (VDF-TrFE-CFE) electroactive polymer nanocomposites with superior electromechanical performance." Journal of Materials Chemistry 22(3): 830-834. https://doi.org/10.1039/C1JM13786G
15. Kohlmeyer, R. R., A. Javadi, B. Pradhan, S. Pilla, K. Setyowati, J. Chen and S. Gong (2009). "Electrical and dielectric properties of hydroxylated carbon nanotube− elastomer composites." The Journal of Physical Chemistry C 113(41): 17626-17629. https://doi.org/10.1021/jp901082c
16. Li, J. (2003). "Exchange coupling in P (VDF-TrFE) copolymer based all-organic composites with giant electrostriction." Physical review letters 90(21): 217601. DOI: 10.1103/PhysRevLett.90.217601
17. Li, M., X. Huang, C. Wu, H. Xu, P. Jiang and T. Tanaka (2012). "Fabrication of two-dimensional hybrid sheets by decorating insulating PANI on reduced graphene oxide for polymer nanocomposites with low dielectric loss and high dielectric constant." Journal of Materials Chemistry 22(44): 23477-23484. https://doi.org/10.1039/C2JM34683D
18. Li, R., C. Xiong, D. Kuang, L. Dong, Y. Lei, J. Yao, M. Jiang and L. Li (2008). "Polyamide 11/poly (vinylidene fluoride) blends as novel flexible materials for capacitors." Macromolecular rapid communications 29(17): 1449-1454. DOI: 10.1002/marc.200800253
19. Maity, N., A. Mandal and A. K. Nandi (2017). "High dielectric poly (vinylidene fluoride) nanocomposite films with MoS 2 using polyaniline interlinker via interfacial interaction." Journal of Materials Chemistry C 5(46): 12121-12133. https://doi.org/10.1039/C7TC03593D
20. Manna, R. and S. K. Srivastava (2017). "Fabrication of functionalized graphene filled carboxylated nitrile rubber nanocomposites as flexible dielectric materials." Materials Chemistry Frontiers 1(4): 780-788. DOI: 10.1039/C6QM00025H
21. Misra, A., P. K. Tyagi, M. K. Singh and D. Misra (2006). "FTIR studies of nitrogen doped carbon nanotubes." Diamond and related materials 15(2-3): 385-388. https://doi.org/10.1016/j.diamond.2005.08.013
22. Molberg, M., D. Crespy, P. Rupper, F. Nüesch, J. A. E. Månson, C. Löwe and D. M. Opris (2010). "High breakdown field dielectric elastomer actuators using encapsulated polyaniline as high dielectric constant filler." Advanced Functional Materials 20(19): 3280-3291. https://doi.org/10.1002/adfm.201000486
23. Rao, Y. and C. Wong (2002). Ultra high dielectric constant epoxy silver composite for embedded capacitor application. 52nd Electronic Components and Technology Conference 2002.(Cat. No. 02CH37345), IEEE. DOI: 10.1109/ECTC.2002.1008210
24. Sain, P., R. Goyal, Y. Prasad, K. Sharma and A. Bhargava (2015). "Few‐layer‐graphene/polycarbonate nanocomposites as dielectric and conducting material." Journal of Applied Polymer Science 132(34). https://doi.org/10.1002/app.42443
25. She, Y., G. Chen and D. Wu (2007). "Fabrication of polyethylene/graphite nanocomposite from modified expanded graphite." Polymer International 56(5): 679-685. https://doi.org/10.1002/pi.2191
26. Stankovich, S., R. D. Piner, S. T. Nguyen and R. S. Ruoff (2006). "Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets." Carbon 44(15): 3342-3347. doi:10.1016/j.carbon.2006.06.004
27. Stobinski, L., B. Lesiak, L. Kövér, J. Tóth, S. Biniak, G. Trykowski and J. Judek (2010). "Multiwall carbon nanotubes purification and oxidation by nitric acid studied by the FTIR and electron spectroscopy methods." Journal of Alloys and Compounds 501(1): 77-84. doi:10.1016/j.jallcom.2010.04.032
28. Taş, M., Z. İşlek Cin, E. D. Sam Parmak and A. Çelik Bedeloğlu (2018). "Fabrication of unilateral conductive and transparent polymer thin films decorated with nanomaterials for flexible electrodes." Polymer Composites 39(5): 1771-1778. https://doi.org/10.1002/pc.24109
29. Thakur, Y., T. Zhang, C. Iacob, T. Yang, J. Bernholc, L. Chen, J. Runt and Q. Zhang (2017). "Enhancement of the dielectric response in polymer nanocomposites with low dielectric constant fillers." Nanoscale 9(31): 10992-10997. DOI: 10.1039/c7nr01932g
30. Tsangaris, G., G. Psarras and N. Kouloumbi (1996). "Evaluation of dielectric behaviour of particulate composites consisting of polymeric matrix and conductive filler." Materials science and technology 12(7): 533-538. https://doi.org/10.1179/mst.1996.12.7.533
31. Tsangaris, G., G. Psarras and N. Kouloumbi (1998). "Electric modulus and interfacial polarization in composite polymeric systems." Journal of Materials Science 33(8): 2027-2037. https://doi.org/10.1023/A:1004398514901
32. Wang, D., Y. Bao, J.-W. Zha, J. Zhao, Z.-M. Dang and G.-H. Hu (2012). "Improved dielectric properties of nanocomposites based on poly (vinylidene fluoride) and poly (vinyl alcohol)-functionalized graphene." ACS applied materials & interfaces 4(11): 6273-6279. https://doi.org/10.1021/am3018652
33. Wang, S., L. Liu, Y. Zeng, B. Zhou, K. Teng, M. Ma, L. Chen and Z. Xu (2015). "Improving dielectric properties of poly (vinylidene fluoride) composites: effects of surface functionalization of exfoliated graphene." Journal of Adhesion Science and Technology 29(7): 678-690. https://doi.org/10.1080/01694243.2014.1003497
34. Wang, T., L. Yuan, G. Liang and A. Gu (2015). "Polyaniline coated carbon nanotube/graphene “sandwich” hybrid and its high-k epoxy composites with low dielectric loss and percolation threshold." Applied Surface Science 359: 754-765. https://doi.org/10.1016/j.apsusc.2015.10.115
35. Worsley, K. A., P. Ramesh, S. K. Mandal, S. Niyogi, M. E. Itkis and R. C. Haddon (2007). "Soluble graphene derived from graphite fluoride." Chemical Physics Letters 445(1-3): 51-56. https://doi.org/10.1016/j.cplett.2007.07.059
36. Wu, C., X. Huang, X. Wu, L. Xie, K. Yang and P. Jiang (2013). "Graphene oxide-encapsulated carbon nanotube hybrids for high dielectric performance nanocomposites with enhanced energy storage density." Nanoscale 5(9): 3847-3855. https://doi.org/10.1039/C3NR00625E
37. Xiao, P., M. Xiao and K. Gong (2001). "Preparation of exfoliated graphite/polystyrene composite by polymerization-filling technique." Polymer 42(11): 4813-4816. https://doi.org/10.1016/S0032-3861(00)00819-3
38. Xie, X.-L., Y.-W. Mai and X.-P. Zhou (2005). "Dispersion and alignment of carbon nanotubes in polymer matrix: a review." Materials science and engineering: R: Reports 49(4): 89-112. https://doi.org/10.1016/j.mser.2005.04.002
39. Xu, W., Y. Ding, Y. Yu, S. Jiang, L. Chen and H. Hou (2017). "Highly foldable PANi@ CNTs/PU dielectric composites toward thin-film capacitor application." Materials Letters 192: 25-28. https://doi.org/10.1016/j.matlet.2017.01.064
40. Yang, C., Y. Lin and C. Nan (2009). "Modified carbon nanotube composites with high dielectric constant, low dielectric loss and large energy density." Carbon 47(4): 1096-1101. https://doi.org/10.1016/j.carbon.2008.12.037
41. Yu, D., J. Wu, L. Zhou, D. Xie and S. Wu (2000). "The dielectric and mechanical properties of a potassium-titanate-whisker-reinforced PP/PA blend." Composites Science and Technology 60(4): 499-508. https://doi.org/10.1016/S0266-3538(99)00149-9
42. Zakaria, M. R., M. H. Abdul Kudus and M. H. Zamri (2017). "Improvement of fracture toughness in epoxy nanocomposites through chemical hybridization of carbon nanotubes and alumina." Materials 10(3): 301. https://doi.org/10.3390/ma10030301
43. Zhang, M., H. Yan, L. Yuan and C. Liu (2016). "Effect of functionalized graphene oxide with hyperbranched POSS polymer on mechanical and dielectric properties of cyanate ester composites." RSC advances 6(45): 38887-38896. https://doi.org/10.1039/C6RA01053A
44. Zhang, Q., H. Li, M. Poh, F. Xia, Z.-Y. Cheng, H. Xu and C. Huang (2002). "An all-organic composite actuator material with a high dielectric constant." Nature 419(6904): 284-287. https://doi.org/10.1038/nature01021
45. Zhao, Y., M. Xiao, S. Wang, X. Ge and Y. Meng (2007). "Preparation and properties of electrically conductive PPS/expanded graphite nanocomposites." Composites science and technology 67(11-12): 2528-2534. doi:10.1016/j.compscitech.2006.12.009
46. Zhu, Y., S. Murali, W. Cai, X. Li, J. W. Suk, J. R. Potts and R. S. Ruoff (2010). "Graphene and graphene oxide: synthesis, properties, and applications." Advanced materials 22(35): 3906-3924. https://doi.org/10.1002/adma.201001068

Polianilin İle Fonksiyonelleştirilmiş Karbon Nanotüp/PDMS Nanokompozitlerin Dielektrik Özellikleri

Year 2020, Volume: 25 Issue: 2, 861 - 874, 31.08.2020

Ömer Faruk Ünsal Yasin Altın Ayşe Bedeloğlu

https://doi.org/10.17482/uumfd.730521

Cited By: 3

Abstract

Son yıllarda, yüksek uzunluk/çap oranı ile hafif ve sağlam kompozitler hazırlanmasını mümkün kılan karbon nanotüpler, yüksek ısıl ve elektriksel iletkenlikleri gibi benzersiz özelliklerinden dolayı iletkenlik veya dielektrik özellikleri yüksek polimer nanokompozitlerin üretiminde kullanılan bir malzeme olarak ortaya çıkmıştır. Bununla birlikte, bu malzemelerle polimerik nanokompozitlerin hazırlanması sırasında bazı problemlerle karşılaşılmaktadır. En büyük sorunlardan biri, bu iletken malzemeleri hazırladıktan veya polimere ekledikten sonra, iletken yapıları
nedeniyle topaklanma, topak oluşturma eğilimi göstermeleridir. Bu nedenle, bu çalışmada ilk olarak, çok duvarlı karbon nanotüpler (MWCNT'ler) polianilinin iletken formu (PANI) ile fonksiyonelleştirilmiştir. Ardından, farklı konsantrasyonlarda fonksiyonelleştirilmiş çok duvarlı karbon nanotüplere sahip nanokompozit poli(dimetil siloksan) (PDMS) polimer filmler hazırlanmıştır. Daha sonra ise, filmlerin yapısal, morfolojik, elektriksel ve dielektrik özellikleri karakterize edilmiştir. Sonuç olarak, sadece % 1,5 PANI-CNT ilavesiyle, PDMS'nin dielektrik sabiti 1 Hz'de 47 kat arttırılmıştır. Burada ortaya konulduğu gibi dielektrik filmler kapasitörler, esnek elektronik, dielektrik elastomer ve yapay kas uygulamalarında kullanılabilir.

Keywords

Karbon Nanotüp (CNTs), İletken Polimer, Dielektrik, Polianilin (PANI), Polimer Nanokompozit, Poli (dimetil siloksan) (PDMS)

Supporting Institution

Bursa Teknik Üniversitesi Bilimsel Araştırma Projeleri Birimi

Project Number

2015-01-008

References

1. Bai, Y., Z.-Y. Cheng, V. Bharti, H. Xu and Q. Zhang (2000). "High-dielectric-constant ceramic-powder polymer composites." Applied Physics Letters 76(25): 3804-3806. https://doi.org/10.1063/1.126787
2. Bodas, D. and C. Khan-Malek (2006). "Formation of more stable hydrophilic surfaces of PDMS by plasma and chemical treatments." Microelectronic engineering 83(4-9): 1277-1279. https://doi.org/10.1016/j.mee.2006.01.195
3. Brochu, P. and Q. Pei (2010). "Advances in dielectric elastomers for actuators and artificial muscles." Macromolecular rapid communications 31(1): 10-36. https://doi.org/10.1002/marc.200900425
4. Brosseau, C., P. Quéffélec and P. Talbot (2001). "Microwave characterization of filled polymers." Journal of Applied Physics 89(8): 4532-4540. https://doi.org/10.1063/1.1343521
5. Carpi, F. and D. D. Rossi (2005). "Improvement of electromechanical actuating performances of a silicone dielectric elastomer by dispersion of titanium dioxide powder." IEEE Transactions on Dielectrics and Electrical Insulation 12(4): 835-843. DOI: 10.1109/TDEI.2005.1511110
6. Chen, G. H., D. J. Wu, W. G. Weng and W. L. Yan (2001). "Preparation of polymer/graphite conducting nanocomposite by intercalation polymerization." Journal of Applied Polymer Science 82(10): 2506-2513. https://doi.org/10.1002/app.2101
7. Dang, Z.-M., J.-K. Yuan, J.-W. Zha, T. Zhou, S.-T. Li and G.-H. Hu (2012). "Fundamentals, processes and applications of high-permittivity polymer–matrix composites." Progress in Materials Science 57(4): 660-723. https://doi.org/10.1016/j.pmatsci.2011.08.001
8. Dang, Z. M., Y. H. Lin and C. W. Nan (2003). "Novel ferroelectric polymer composites with high dielectric constants." Advanced Materials 15(19): 1625-1629. https://doi.org/10.1002/adma.200304911
9. Dang, Z. M., L. Wang, Y. Yin, Q. Zhang and Q. Q. Lei (2007). "Giant dielectric permittivities in functionalized carbon‐nanotube/electroactive‐polymer nanocomposites." Advanced Materials 19(6): 852-857. DOI: 10.1002/adma.200600703
10. Fan, P., L. Wang, S. Jia, F. Chen, J. Yang and M. Zhong (2017). "Encapsulated graphenes through ultrasonically initiated in situ polymerization: A route to high dielectric permittivity, low loss materials with low percolation threshold." Journal of Applied Polymer Science 134(12). https://doi.org/10.1002/app.44628
11. Huang, C. and Q. Zhang (2004). "Enhanced dielectric and electromechanical responses in high dielectric constant all‐polymer percolative composites." Advanced Functional Materials 14(5): 501-506. https://doi.org/10.1002/adfm.200305021
12. Huang, C., Q. Zhang, J. Y. Li and M. Rabeony (2005). "Colossal dielectric and electromechanical responses in self-assembled polymeric nanocomposites." Applied Physics Letters 87(18): 182901. DOI:10.1063/1.2105997
13. Huang, C., Q. Zhang and J. Su (2003). "High-dielectric-constant all-polymer percolative composites." Applied Physics Letters 82(20): 3502-3504. https://doi.org/10.1063/1.1575505
14. Javadi, A., Y. Xiao, W. Xu and S. Gong (2012). "Chemically modified graphene/P (VDF-TrFE-CFE) electroactive polymer nanocomposites with superior electromechanical performance." Journal of Materials Chemistry 22(3): 830-834. https://doi.org/10.1039/C1JM13786G
15. Kohlmeyer, R. R., A. Javadi, B. Pradhan, S. Pilla, K. Setyowati, J. Chen and S. Gong (2009). "Electrical and dielectric properties of hydroxylated carbon nanotube− elastomer composites." The Journal of Physical Chemistry C 113(41): 17626-17629. https://doi.org/10.1021/jp901082c
16. Li, J. (2003). "Exchange coupling in P (VDF-TrFE) copolymer based all-organic composites with giant electrostriction." Physical review letters 90(21): 217601. DOI: 10.1103/PhysRevLett.90.217601
17. Li, M., X. Huang, C. Wu, H. Xu, P. Jiang and T. Tanaka (2012). "Fabrication of two-dimensional hybrid sheets by decorating insulating PANI on reduced graphene oxide for polymer nanocomposites with low dielectric loss and high dielectric constant." Journal of Materials Chemistry 22(44): 23477-23484. https://doi.org/10.1039/C2JM34683D
18. Li, R., C. Xiong, D. Kuang, L. Dong, Y. Lei, J. Yao, M. Jiang and L. Li (2008). "Polyamide 11/poly (vinylidene fluoride) blends as novel flexible materials for capacitors." Macromolecular rapid communications 29(17): 1449-1454. DOI: 10.1002/marc.200800253
19. Maity, N., A. Mandal and A. K. Nandi (2017). "High dielectric poly (vinylidene fluoride) nanocomposite films with MoS 2 using polyaniline interlinker via interfacial interaction." Journal of Materials Chemistry C 5(46): 12121-12133. https://doi.org/10.1039/C7TC03593D
20. Manna, R. and S. K. Srivastava (2017). "Fabrication of functionalized graphene filled carboxylated nitrile rubber nanocomposites as flexible dielectric materials." Materials Chemistry Frontiers 1(4): 780-788. DOI: 10.1039/C6QM00025H
21. Misra, A., P. K. Tyagi, M. K. Singh and D. Misra (2006). "FTIR studies of nitrogen doped carbon nanotubes." Diamond and related materials 15(2-3): 385-388. https://doi.org/10.1016/j.diamond.2005.08.013
22. Molberg, M., D. Crespy, P. Rupper, F. Nüesch, J. A. E. Månson, C. Löwe and D. M. Opris (2010). "High breakdown field dielectric elastomer actuators using encapsulated polyaniline as high dielectric constant filler." Advanced Functional Materials 20(19): 3280-3291. https://doi.org/10.1002/adfm.201000486
23. Rao, Y. and C. Wong (2002). Ultra high dielectric constant epoxy silver composite for embedded capacitor application. 52nd Electronic Components and Technology Conference 2002.(Cat. No. 02CH37345), IEEE. DOI: 10.1109/ECTC.2002.1008210
24. Sain, P., R. Goyal, Y. Prasad, K. Sharma and A. Bhargava (2015). "Few‐layer‐graphene/polycarbonate nanocomposites as dielectric and conducting material." Journal of Applied Polymer Science 132(34). https://doi.org/10.1002/app.42443
25. She, Y., G. Chen and D. Wu (2007). "Fabrication of polyethylene/graphite nanocomposite from modified expanded graphite." Polymer International 56(5): 679-685. https://doi.org/10.1002/pi.2191
26. Stankovich, S., R. D. Piner, S. T. Nguyen and R. S. Ruoff (2006). "Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets." Carbon 44(15): 3342-3347. doi:10.1016/j.carbon.2006.06.004
27. Stobinski, L., B. Lesiak, L. Kövér, J. Tóth, S. Biniak, G. Trykowski and J. Judek (2010). "Multiwall carbon nanotubes purification and oxidation by nitric acid studied by the FTIR and electron spectroscopy methods." Journal of Alloys and Compounds 501(1): 77-84. doi:10.1016/j.jallcom.2010.04.032
28. Taş, M., Z. İşlek Cin, E. D. Sam Parmak and A. Çelik Bedeloğlu (2018). "Fabrication of unilateral conductive and transparent polymer thin films decorated with nanomaterials for flexible electrodes." Polymer Composites 39(5): 1771-1778. https://doi.org/10.1002/pc.24109
29. Thakur, Y., T. Zhang, C. Iacob, T. Yang, J. Bernholc, L. Chen, J. Runt and Q. Zhang (2017). "Enhancement of the dielectric response in polymer nanocomposites with low dielectric constant fillers." Nanoscale 9(31): 10992-10997. DOI: 10.1039/c7nr01932g
30. Tsangaris, G., G. Psarras and N. Kouloumbi (1996). "Evaluation of dielectric behaviour of particulate composites consisting of polymeric matrix and conductive filler." Materials science and technology 12(7): 533-538. https://doi.org/10.1179/mst.1996.12.7.533
31. Tsangaris, G., G. Psarras and N. Kouloumbi (1998). "Electric modulus and interfacial polarization in composite polymeric systems." Journal of Materials Science 33(8): 2027-2037. https://doi.org/10.1023/A:1004398514901
32. Wang, D., Y. Bao, J.-W. Zha, J. Zhao, Z.-M. Dang and G.-H. Hu (2012). "Improved dielectric properties of nanocomposites based on poly (vinylidene fluoride) and poly (vinyl alcohol)-functionalized graphene." ACS applied materials & interfaces 4(11): 6273-6279. https://doi.org/10.1021/am3018652
33. Wang, S., L. Liu, Y. Zeng, B. Zhou, K. Teng, M. Ma, L. Chen and Z. Xu (2015). "Improving dielectric properties of poly (vinylidene fluoride) composites: effects of surface functionalization of exfoliated graphene." Journal of Adhesion Science and Technology 29(7): 678-690. https://doi.org/10.1080/01694243.2014.1003497
34. Wang, T., L. Yuan, G. Liang and A. Gu (2015). "Polyaniline coated carbon nanotube/graphene “sandwich” hybrid and its high-k epoxy composites with low dielectric loss and percolation threshold." Applied Surface Science 359: 754-765. https://doi.org/10.1016/j.apsusc.2015.10.115
35. Worsley, K. A., P. Ramesh, S. K. Mandal, S. Niyogi, M. E. Itkis and R. C. Haddon (2007). "Soluble graphene derived from graphite fluoride." Chemical Physics Letters 445(1-3): 51-56. https://doi.org/10.1016/j.cplett.2007.07.059
36. Wu, C., X. Huang, X. Wu, L. Xie, K. Yang and P. Jiang (2013). "Graphene oxide-encapsulated carbon nanotube hybrids for high dielectric performance nanocomposites with enhanced energy storage density." Nanoscale 5(9): 3847-3855. https://doi.org/10.1039/C3NR00625E
37. Xiao, P., M. Xiao and K. Gong (2001). "Preparation of exfoliated graphite/polystyrene composite by polymerization-filling technique." Polymer 42(11): 4813-4816. https://doi.org/10.1016/S0032-3861(00)00819-3
38. Xie, X.-L., Y.-W. Mai and X.-P. Zhou (2005). "Dispersion and alignment of carbon nanotubes in polymer matrix: a review." Materials science and engineering: R: Reports 49(4): 89-112. https://doi.org/10.1016/j.mser.2005.04.002
39. Xu, W., Y. Ding, Y. Yu, S. Jiang, L. Chen and H. Hou (2017). "Highly foldable PANi@ CNTs/PU dielectric composites toward thin-film capacitor application." Materials Letters 192: 25-28. https://doi.org/10.1016/j.matlet.2017.01.064
40. Yang, C., Y. Lin and C. Nan (2009). "Modified carbon nanotube composites with high dielectric constant, low dielectric loss and large energy density." Carbon 47(4): 1096-1101. https://doi.org/10.1016/j.carbon.2008.12.037
41. Yu, D., J. Wu, L. Zhou, D. Xie and S. Wu (2000). "The dielectric and mechanical properties of a potassium-titanate-whisker-reinforced PP/PA blend." Composites Science and Technology 60(4): 499-508. https://doi.org/10.1016/S0266-3538(99)00149-9
42. Zakaria, M. R., M. H. Abdul Kudus and M. H. Zamri (2017). "Improvement of fracture toughness in epoxy nanocomposites through chemical hybridization of carbon nanotubes and alumina." Materials 10(3): 301. https://doi.org/10.3390/ma10030301
43. Zhang, M., H. Yan, L. Yuan and C. Liu (2016). "Effect of functionalized graphene oxide with hyperbranched POSS polymer on mechanical and dielectric properties of cyanate ester composites." RSC advances 6(45): 38887-38896. https://doi.org/10.1039/C6RA01053A
44. Zhang, Q., H. Li, M. Poh, F. Xia, Z.-Y. Cheng, H. Xu and C. Huang (2002). "An all-organic composite actuator material with a high dielectric constant." Nature 419(6904): 284-287. https://doi.org/10.1038/nature01021
45. Zhao, Y., M. Xiao, S. Wang, X. Ge and Y. Meng (2007). "Preparation and properties of electrically conductive PPS/expanded graphite nanocomposites." Composites science and technology 67(11-12): 2528-2534. doi:10.1016/j.compscitech.2006.12.009
46. Zhu, Y., S. Murali, W. Cai, X. Li, J. W. Suk, J. R. Potts and R. S. Ruoff (2010). "Graphene and graphene oxide: synthesis, properties, and applications." Advanced materials 22(35): 3906-3924. https://doi.org/10.1002/adma.201001068

There are 46 citations in total.

Details

Primary Language	English
Subjects	Polymer Science and Technologies, Composite and Hybrid Materials, Nanotechnology
Journal Section	Research Articles
Authors	Ömer Faruk Ünsal 0000-0001-8405-3676 Yasin Altın 0000-0002-8554-3025 Ayşe Bedeloğlu 0000-0003-2960-5188
Project Number	2015-01-008
Publication Date	August 31, 2020
Submission Date	May 1, 2020
Acceptance Date	July 11, 2020
Published in Issue	Year 2020 Volume: 25 Issue: 2

Cite

APA	Ünsal, Ö. F., Altın, Y., & Bedeloğlu, A. (2020). DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, 25(2), 861-874. https://doi.org/10.17482/uumfd.730521
AMA	Ünsal ÖF, Altın Y, Bedeloğlu A. DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES. UUJFE. August 2020;25(2):861-874. doi:10.17482/uumfd.730521
Chicago	Ünsal, Ömer Faruk, Yasin Altın, and Ayşe Bedeloğlu. “DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 25, no. 2 (August 2020): 861-74. https://doi.org/10.17482/uumfd.730521.
EndNote	Ünsal ÖF, Altın Y, Bedeloğlu A (August 1, 2020) DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 25 2 861–874.
IEEE	Ö. F. Ünsal, Y. Altın, and A. Bedeloğlu, “DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES”, UUJFE, vol. 25, no. 2, pp. 861–874, 2020, doi: 10.17482/uumfd.730521.
ISNAD	Ünsal, Ömer Faruk et al. “DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 25/2 (August 2020), 861-874. https://doi.org/10.17482/uumfd.730521.
JAMA	Ünsal ÖF, Altın Y, Bedeloğlu A. DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES. UUJFE. 2020;25:861–874.
MLA	Ünsal, Ömer Faruk et al. “DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, vol. 25, no. 2, 2020, pp. 861-74, doi:10.17482/uumfd.730521.
Vancouver	Ünsal ÖF, Altın Y, Bedeloğlu A. DIELECTRIC PROPERTIES OF POLYANILINE-FUNCTIONALIZED CARBON NANOTUBE/PDMS NANOCOMPOSITES. UUJFE. 2020;25(2):861-74.

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