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Usage of acetic acid for boric acid production from boron wastes

Year 2022, Volume: 11 Issue: 3, 819 - 825, 18.07.2022
https://doi.org/10.28948/ngumuh.1088309

Abstract

Turkey's boric acid production has the highest production share among refined boron products. This production is takes place at the Bandırma (Balıkesir) and Emet (Kütahya) Boric Acid Plants of ETI Maden Operations. Concentrated ore (by physical processes) and high-grade wastes accumulated in waste ponds/dams are obtained from boron production plants. In this study, slime size (d80=52.70μm) wastes belonging to the Bigadiç field with 9-12% B2O3 (ulexite-colemanite) content have been evaluated. Due to the small size of feeding without the need for grinding, the sample was subjected to leaching of acetic acid at 60°C for 1 hour, at a mixing speed of 1500 rpm, at 7% solids. In addition to the recovery of 90% H3BO3 (at 4% acid concentration) after the leaching process, different compounds such as Na2O, and CaO were also obtained. Similar peaks were found in the FT-IR analyzes of boric acid and the product obtained. This study is an important output in terms of evaluating the % B2O3 content in the wastes of both this plant and other boron plants.

References

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  • G. Sertkaya and B. Bayat, “Kolemanit Atıklarından Biyoliç Yöntemi ile Borik Asit Eldesi/Production of Boric Acid From Colemanite Wastes by Bioleaching tailings,” Ç.U. Sci., vol. 17, no. 7, pp. 1–10, 2008.
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  • Y. Erdoğan, A. Olgun, F. Özmal, and B. Zeybek, “Utilization of Boron Industry Wastes, Fly Ash, Bottom Ash and Alunite Mineral in Cement Production as an Additive Material,” 455-461, 2nd International Boron Symposium, 2004.
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  • C. Helvacı, “Bor madenciliğinde işletme, zenginleştirme ve pazarlama sorunları, Mining, Dressing and Marketing problems of Borate Minerals (in Turkish),” in 3rd International Boron Symposium, 2006, pp. 559–571.
  • Ö. Gülsoy, L. Ergün, M. Can, A. Mergen, T. Ergül, and T. Aydın, “Bigadiç bor konsantratörü için alternatif zenginleştime yöntemi (in Turkish),” in 3. International Boron Symposium, 2006, pp. 307–313.
  • C. Helvacı, “Bor Yataklarini İçeren Neojen Havzalarinin Jeoloji̇ Özelli̇kleri̇: Yataklarin Genel Değerlendi̇rmesi̇ ve Gelecek Öngörüsü,Türki̇ye,” Maden Tetk. ve Aram. Derg., vol. 0, no. 151, 2015, doi: 10.19076/mta.75175.
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  • M. Özdemir and N. U. Öztürk, “Utilization of clay wastes containing boron as cement additives,” Cem. Concr. Res., vol. 33, no. 10, pp. 1659–1661, 2003, doi: 10.1016/S0008-8846(03)00138-8.
  • E. Yoğurtcuoğlu, “Üleksit-Kolemanit İçeren Bor Şlam Atıklarından Borun Geri Kazanımı/Recovery of Boron from Boron Slurry Wastes Containing Ulexite-Colemanit (in Turkish),” in International Turkic World Congress on Science and Engineering, 2019, pp. 1262–1267.
  • T. Batar, S. Bayça, Ö. Solak, E. Sayın, E. Can, and B. Kahraman, “Effects of boron ore and its tailings to the ceramic wall tile structure (in Turkish).,” in 6th International Industrial Minerals Symposium, 2007, pp. 328–333.
  • E. Sayın, T. Batar, Ö. Solak, A. Yamık, and M. B. Tufan, “Use of tincal ore and boron tailings in ceramic paste and water insulating mortar (in Turkish),” in 6th International Industrial Minerals Symposium, 2007, pp. 428–437.
  • İ. Bentli, O. Özdemir, M. S. Çelik, and N. Ediz, “Bor Atıkları ve Değerlendirilme Stratejileri Boron Tailings and Evaluation Strategies,” in The First International Boron Symposium, 2001, pp. 250–258.
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  • N. Ediz and H. Özdag, “Etibor A.Ş. Kırka Boraks İsletmesi Tinkal Cevheri ve Atıklarının Doğrudan Zenginleştrilmesi/Direct Processing of Tincal Ores and the Wastes of the Etibor A.S. Kırka Borax Mine,” Turkish J. Eng. Env. Sci., vol. 26, pp. 107–116, 2002.
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  • S. U. Bayca, “Recovery of Boric Acid From Colemanite Waste by Sulfuric Acid Leaching and Crystallization,” pp. 793–804, 2007.
  • A. N. Bulutcu, C. O. Ertekin, and M. B. Kuskay Celikoyan, “Impurity control in the production of boric acid from colemanite in the presence of propionic acid,” Chem. Eng. Process. Process Intensif., vol. 47, no. 12, pp. 2270–2274, 2008, doi: 10.1016/j.cep.2007.12.012.
  • B. Kuşkay Çelikoyan and A. N. Bulutcu, “Kolemanitten yeni bir yöntemle borik asit üretim prosesinin geliştirilmesi/Development of a new method for the boric acid production process from colemanite ore (in Turkish),” İTU J., vol. 9, no. 2, pp. 15–26, 2010.
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Bor atıklarından borik asit üretiminde asetik asidin kullanımı

Year 2022, Volume: 11 Issue: 3, 819 - 825, 18.07.2022
https://doi.org/10.28948/ngumuh.1088309

Abstract

Türkiye'nin borik asit üretimi rafine bor ürünleri arasında en yüksek üretim payına sahiptir. Söz konusu bu üretim ETİ Maden İşletmelerinin Bandırma (Balıkesir) ve Emet (Kütahya) Borik Asit Tesislerinden üretilmektedir. Bor üretim tesislerinden konsantre cevher (fiziksel işlemlerle) ve atık havuzlarında/barajlarda biriktirilen yüksek tenörlü atıklar elde edilmektedir. Bu çalışmada, Bigadiç sahasına ait %9-12 B2O3 (üleksit-kolemanit) içeriğine sahip şlam boyutundaki (d90=81.94μm) atıklar değerlendirilmiştir. Numune, öğütülmeye ihtiyaç duyulmadan küçük besleme boyutundan dolayı 60°C'de 1 saat, 1500 rpm karıştırma hızında, %7 katı oranında asetik asit liç işlemine tabi tutulmuştur. Liç işlemi sonrasında %90 H3BO3 (%4 asit konsantrasyonunda) veriminin yanı sıra Na2O ve CaO gibi farklı bileşikler de elde edilmiştir. Borik asit ve elde edilen ürünün FT-IR analizlerinde benzer pikler bulunmuştur. Bu çalışma, hem bu tesisin hem de diğer bor tesislerinin atıklarındaki % B2O3 içeriğinin değerlendirilmesi açısından önemli bir çıktıdır.

References

  • V. Arslan and O. Bayat, “Kolemanit Cevherinden Oksalik Asit Liçi ile Borik Asit Eldesi (in Turkish), Production of Boric Acid From Colemanite Ore by Oxalic Acid Leaching,” J. Undergr. Resour. Altı Kaynakları Derg., no. 10, pp. 11–20, 2016, Accessed: Dec. 07, 2021. [Online]. Available: www.mtbilimsel.com.
  • BSR, “Bor Sektör Raporu/Boron Sector Report 2020,” Ankara, Turkey, 2020.
  • T. Guyaguler, “Türkiye bor potansiyeli,” in 4. Industrial Mineral Symposium, 2001, pp. 18–27.
  • S. G. Ozkan, “Comparison of Magnetic Separation and Flotation Results for Beneficiation of Emet Colemanite Ores,” Magn. Electr. Sep., vol. 10, no. 4, pp. 213–221, 2001, doi: 10.1155/2001/10257.
  • N. Acarkan, “Boron Products and Their Uses/Bor ürün çeşitleri ve kullanım alanları (in Turkish),” I. Uluslararası Bor Sempozyumu, pp. 1–5, 2002.
  • C. Bilal, “Kolemanitin Sülfürik Asit ile Reaksiyon Kinetiğinin İncelenmesi/The reaction kinetics of colemanite with sulfuric acid (in Turkish),” ITU, Istanbul, 2003.
  • C. Helvacı, “Turkish borate deposits : Geological setting, economic importance and boron policy/ Türkiye Borat Yatakları: Jeolojik Konumu, Ekonomik Önemi ve Bor Politikası (in Turkish),” in 5th Industrial Minerals Symp., 2004, pp. 11–27.
  • F. Göktepe, “Bigadiç bor atıklarının flotasyonla zenginleştirilebilirliğinin ön araştırması/Concentration Study of Bigadiç Boron Tailings by Flotation (in Turkish),” in 2nd International Boron Symposium, 2004, pp. 81–86.
  • E. Yoğurtcuoğlu and O. Dalgalı, “Evaluation of Bigadiç Colemanite and Ulexite Slurry Wastes by Heap Leach/Bigadiç kolemanit ve üleksit şlam atıklarının yığın liçi ile değerlendirilmesi (in Turkish),” in International Boron Symposium, 2019, pp. 102–106.
  • E. Yoğurtcuoğlu, “Bigadiç Bor Atıklarından Sitrik Asit ile Borik Asit Elde Edilmesi/The Production of Boric Acid with Citric Acid from Bigadic Bor Wastes (in Turkish),” in 1st Intarnational Conference on Environment, Technology and Management (ICETEM), 2019, pp. 1054–1060.
  • C. Ozmetin, M. M. Kocakerim, S. Yapıcı, and A. Yartaşı, “A Semiempirical Kinetic Model for Dissolution of Colemanite in Aqueous CH3COOH Solutions,” Ind. Eng. Chem. Res., vol. 35, no. 7, pp. 2355–2359, 1996.
  • G. Sertkaya and B. Bayat, “Kolemanit Atıklarından Biyoliç Yöntemi ile Borik Asit Eldesi/Production of Boric Acid From Colemanite Wastes by Bioleaching tailings,” Ç.U. Sci., vol. 17, no. 7, pp. 1–10, 2008.
  • C. Helvacı, “Borate deposits: An overview and future forecast with regard to mineral deposits,” J. Boron, vol. 2, no. 2, pp. 59–70, 2017, [Online]. Available: https://dergipark.org.tr/boron/issue/31236/302668.
  • Y. Erdoğan, A. Olgun, F. Özmal, and B. Zeybek, “Utilization of Boron Industry Wastes, Fly Ash, Bottom Ash and Alunite Mineral in Cement Production as an Additive Material,” 455-461, 2nd International Boron Symposium, 2004.
  • A. T. Baydır and Y. Erdoğan, “Dissolution Of The Rubidium From Eti Mine Kırka Boron Management Waste,” Afyon Kocatepe Univ. J. Sci. Eng., vol. 13, no. 2, pp. 13–20, 2013, doi: 10.5578/fmbd.6511.
  • B. Yaman and N. Çalış Açıkbaş, “Dry Sliding Behaviour of Boron Waste Reinforced Epoxy Matrix Composites,” J. Boron, vol. 3, no. 2, pp. 63–70, 2018, doi: 10.30728/boron.343608.
  • R. Boncukcuoǧlu, M. M. Kocakerim, E. Kocadaǧistan, and M. T. Yilmaz, “Recovery of boron of the sieve reject in the production of borax,” Resour. Conserv. Recycl., vol. 37, no. 2, pp. 147–157, 2003, doi: 10.1016/S0921-3449(02)00072-1.
  • I. Y. Elbeyli, “Production of crystalline boric acid and sodium citrate from borax decahydrate,” Hydrometallurgy, vol. 158, pp. 19–26, 2015, doi: 10.1016/j.hydromet.2015.09.022.
  • H. Tüzün, S. Ün, and Ş. Buğdaycı, “Konsantre ve Rafine Bor Ürünler,” in International Symposium on Boron, 2019, pp. 63–70.
  • C. Helvacı, “Türkiye Borat Yatakları Jeolojik Konumu, Ekonomik Önemi ve Bor Politikası,” Balıkesir Üniversitesi Fen Bilim. Enstitüsü Derg., vol. 5, no. 1, pp. 4–41, 2003.
  • C. Helvacı, “Bor madenciliğinde işletme, zenginleştirme ve pazarlama sorunları, Mining, Dressing and Marketing problems of Borate Minerals (in Turkish),” in 3rd International Boron Symposium, 2006, pp. 559–571.
  • Ö. Gülsoy, L. Ergün, M. Can, A. Mergen, T. Ergül, and T. Aydın, “Bigadiç bor konsantratörü için alternatif zenginleştime yöntemi (in Turkish),” in 3. International Boron Symposium, 2006, pp. 307–313.
  • C. Helvacı, “Bor Yataklarini İçeren Neojen Havzalarinin Jeoloji̇ Özelli̇kleri̇: Yataklarin Genel Değerlendi̇rmesi̇ ve Gelecek Öngörüsü,Türki̇ye,” Maden Tetk. ve Aram. Derg., vol. 0, no. 151, 2015, doi: 10.19076/mta.75175.
  • Boron as the Rising Value of Turkey https://www.etimaden.gov.tr/en/boron-in-turkey Accessed 18.01.2022
  • M. Özdemir and N. U. Öztürk, “Utilization of clay wastes containing boron as cement additives,” Cem. Concr. Res., vol. 33, no. 10, pp. 1659–1661, 2003, doi: 10.1016/S0008-8846(03)00138-8.
  • E. Yoğurtcuoğlu, “Üleksit-Kolemanit İçeren Bor Şlam Atıklarından Borun Geri Kazanımı/Recovery of Boron from Boron Slurry Wastes Containing Ulexite-Colemanit (in Turkish),” in International Turkic World Congress on Science and Engineering, 2019, pp. 1262–1267.
  • T. Batar, S. Bayça, Ö. Solak, E. Sayın, E. Can, and B. Kahraman, “Effects of boron ore and its tailings to the ceramic wall tile structure (in Turkish).,” in 6th International Industrial Minerals Symposium, 2007, pp. 328–333.
  • E. Sayın, T. Batar, Ö. Solak, A. Yamık, and M. B. Tufan, “Use of tincal ore and boron tailings in ceramic paste and water insulating mortar (in Turkish),” in 6th International Industrial Minerals Symposium, 2007, pp. 428–437.
  • İ. Bentli, O. Özdemir, M. S. Çelik, and N. Ediz, “Bor Atıkları ve Değerlendirilme Stratejileri Boron Tailings and Evaluation Strategies,” in The First International Boron Symposium, 2001, pp. 250–258.
  • G. Sertkaya, “Kolemanit atıklardan biyoliç yöntemi ile borik asit eldesi/Production of boric acid from colemanite wastes by bioleaching tailings (in Turkish),” Çukurova University, 2007.
  • N. Ediz and H. Özdag, “Etibor A.Ş. Kırka Boraks İsletmesi Tinkal Cevheri ve Atıklarının Doğrudan Zenginleştrilmesi/Direct Processing of Tincal Ores and the Wastes of the Etibor A.S. Kırka Borax Mine,” Turkish J. Eng. Env. Sci., vol. 26, pp. 107–116, 2002.
  • A. Ekmekyapar, N. Demirkiran, and A. Künkül, “Dissolution kinetics of ulexite in acetic acid solutions,” Chem. Eng. Res. Des., vol. 86, no. 9, pp. 1011–1016, 2008, doi: 10.1016/j.cherd.2008.04.005.
  • S. U. Bayca, “Recovery of Boric Acid From Colemanite Waste by Sulfuric Acid Leaching and Crystallization,” pp. 793–804, 2007.
  • A. N. Bulutcu, C. O. Ertekin, and M. B. Kuskay Celikoyan, “Impurity control in the production of boric acid from colemanite in the presence of propionic acid,” Chem. Eng. Process. Process Intensif., vol. 47, no. 12, pp. 2270–2274, 2008, doi: 10.1016/j.cep.2007.12.012.
  • B. Kuşkay Çelikoyan and A. N. Bulutcu, “Kolemanitten yeni bir yöntemle borik asit üretim prosesinin geliştirilmesi/Development of a new method for the boric acid production process from colemanite ore (in Turkish),” İTU J., vol. 9, no. 2, pp. 15–26, 2010.
  • B. Kuskay and A. N. Bulutcu, “Design parameters of boric acid production process from colemanite ore in the presence of propionic acid,” Chem. Eng. Process. Process Intensif., vol. 50, no. 4, pp. 377–383, 2011, doi: 10.1016/j.cep.2011.02.013.
  • O. Laçin, B. Dönmez, and F. Demir, “Dissolution kinetics of natural magnesite in acetic acid solutions,” Int. J. Miner. Process., vol. 75, no. 1–2, pp. 91–99, 2005, doi: 10.1016/j.minpro.2004.05.002.
  • B. Dönmez, F. Demir, and O. Laçin, “Leaching kinetics of calcined magnesite in acetic acid solutions,” J. Ind. Eng. Chem., vol. 15, no. 6, pp. 865–869, 2009, doi: 10.1016/j.jiec.2009.09.014.
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There are 52 citations in total.

Details

Primary Language English
Subjects Engineering, Chemical Engineering, Material Production Technologies
Journal Section Materials and Metallurgical Engineering
Authors

Emine Yoğurtcuoğlu 0000-0002-9961-8809

Publication Date July 18, 2022
Submission Date March 15, 2022
Acceptance Date April 26, 2022
Published in Issue Year 2022 Volume: 11 Issue: 3

Cite

APA Yoğurtcuoğlu, E. (2022). Usage of acetic acid for boric acid production from boron wastes. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 11(3), 819-825. https://doi.org/10.28948/ngumuh.1088309
AMA Yoğurtcuoğlu E. Usage of acetic acid for boric acid production from boron wastes. NOHU J. Eng. Sci. July 2022;11(3):819-825. doi:10.28948/ngumuh.1088309
Chicago Yoğurtcuoğlu, Emine. “Usage of Acetic Acid for Boric Acid Production from Boron Wastes”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 11, no. 3 (July 2022): 819-25. https://doi.org/10.28948/ngumuh.1088309.
EndNote Yoğurtcuoğlu E (July 1, 2022) Usage of acetic acid for boric acid production from boron wastes. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 11 3 819–825.
IEEE E. Yoğurtcuoğlu, “Usage of acetic acid for boric acid production from boron wastes”, NOHU J. Eng. Sci., vol. 11, no. 3, pp. 819–825, 2022, doi: 10.28948/ngumuh.1088309.
ISNAD Yoğurtcuoğlu, Emine. “Usage of Acetic Acid for Boric Acid Production from Boron Wastes”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 11/3 (July 2022), 819-825. https://doi.org/10.28948/ngumuh.1088309.
JAMA Yoğurtcuoğlu E. Usage of acetic acid for boric acid production from boron wastes. NOHU J. Eng. Sci. 2022;11:819–825.
MLA Yoğurtcuoğlu, Emine. “Usage of Acetic Acid for Boric Acid Production from Boron Wastes”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, vol. 11, no. 3, 2022, pp. 819-25, doi:10.28948/ngumuh.1088309.
Vancouver Yoğurtcuoğlu E. Usage of acetic acid for boric acid production from boron wastes. NOHU J. Eng. Sci. 2022;11(3):819-25.

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