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Antibacterial and Optical Properties of Mn Doped ZnO Nanopowders Synthesized via Spray Drying and Subsequent Thermal Decomposition

Year 2020, Volume: 35 Issue: 4, 1073 - 1082, 31.12.2020

Şeyma Duman Büşra Bulut Burak Özkal

https://doi.org/10.21605/cukurovaummfd.869176
Cited By: 2

Abstract

Mn doped ZnO nanopowders with homogenous particle distribution were synthesized using spray drying and thermal decomposition dual methods. Synthesis was carried out in spray drying slurry containing zinc acetate powders followed by calcining the as-prepared powders at 300, 400, and 500oC. Mn doping was achieved by adding manganese (II) acetate at different concentrations between 0.01-0.05 M during the synthesis. The obtained powders were characterized by a variety of characterization techniques. The results of phase analysis revealed that Mn-doped ZnO nanopowders having a single hexagonal structured ZnO phase. According to the results of microstructural and UV-vis characterizations; morphologies and optical properties of the Mn-doped ZnO nanopowders were affected by Mn doping. Furthermore, the results of this study exhibited that the addition of Mn have a significant influence on the antibacterial performance of the synthesized ZnO nanopowders.

Keywords

Mn doped ZnO Spray drying Optical properties Antibacterial properties

References

  • 1. Ozgur U., Alivov Y.I., Liu C., Take A., Reshchikov M.A., Dogan S., Avrutin V., Cho S.J., Markoc H., 2005. A Comprehensive Review of ZnO Materials and Devices, Journal of Applied Physics, 98, 041301.
  • 2. Khosravi-Gandomani S., Yousefi R., Jamali- Sheini F., Huang N.M., 2014. Optical and Electrical Properties of P-type Ag-doped ZnO Nanostructures, Ceramics International, 40, 7957-7963.
  • 3. Yousefi, R., Jamli-Sheini, F., 2012. Effect of Chlorine Ion Concentration on Morphology and Optical Properties of Cl-doped ZnO Nanostructures, Ceramics International, 38(7), 5821-5825.
  • 4. Ravichandran, K., Karthika, K., Sakthivel, B., Jabena Begum, N., Snega, S., Swaminathan, K., Senthamilselvi, V., 2014. Tuning the Combined Magnetic and Antibacterial Properties of ZnO Nanopowders Through Mn Doping for Biomedical Applications, Journal of Magnetism and Magnetic Materials, 358-359, 50–55.
  • 5. Mote, V.D., Dargad, J.S., Purushotham, Y., Dole, B.N., 2015. Effect of Doping on Structural, Physical, Morphological and Optical Properties of Zn1-xMnxO Nano- particles, Ceramics International, 41, 15153–15161.
  • 6. Omri, K., El, Ghoul, J., Lemine, O.M., Bououdina, M., Zhang, B., El Mira, L., 2013. Magnetic and Optical Properties of Manganese Doped ZnO Nanoparticles Synthesized by Sol– gel Technique, Superlattices and Microstructures 60, 139–147.
  • 7. Ma, X., Wang, Z., 2011. The UV and Blue Light Emission Properties of Mn Doped ZnO Nanocrystals, Microelectronic Engineering, 88(10), 3168-3171.
  • 8. Bhat, S.V., Deepak, F.L., 2005. Tuning the Bandgap of ZnO by Substitution with Mn2+, Co2+ and Ni2+, Solid State Communications, 135(6), 345-347.
  • 9. Senthilkumaar, S., Rajendran, K., Banerjee, S., Chinic, T.K., Sengodan, V., 2008. Influence of Mn Doping on the Microstructure and Optical Property of ZnO, Materials Science in Semiconductor Processing, 11(1) 6-12.
  • 10. Vethanathan, S.J.K., Brightson, M., Sundar, S.M., Perumal, S., 2011. Synthesis of Mn Doped ZnO Nanocrystals by Solvothermal Route and its Characterization, Materials Chemistry and Physics, 125, 872–875.
  • 11. Jiang, Y.J., Wang, W., Jing, C.B., Cao, C.Y., Chu, J.H., 2011. Sol-gel Synthesis, Structure and Magnetic Properties of Mn-doped ZnO Diluted Magnetic Semiconductors, Materials Science and Engineering: B 176, 1301–1306.
  • 12. Yan, H.L., Wang, J.B., Zhong, X.L., 2011. Zn- catalyzed Growth Processes and Ferromagnetism of Mn-doped ZnO Nanorods on Si Substrate, Applied Surface Science, 257, 5017–5020.
  • 13. Duman, Ş., Ozkal, B., 2016. Powder State Characterization of ZnO/C and NiO/C Composite Nanopowders Synthesized Via Spray Drying Subsequent Thermal Decomposition, XIII. International Congress Winter Session ‘Machines, Technologies, Materials’ (MTM 2016), 14-17 September 2016, Varna – Bulgaria, 36-39.
  • 14. Duman, Ş., Ozkal, B., 2016. Effect of Dopant and Binder on the Formation of ZnO Powders During Thermal Decomposition of Spray Dried Zinc-acetate Based Granules, Journal of Optoelectronics and Advanced Materials, 18, 705-711.
  • 15. Bertrand, G., Roy, P., Filiatre, V., Coddet, C., 2005. Spray-dried Ceramic Powders: A Quantitative Correlation Between Slurry Characteristics and Shapes of the Granules, Chemical Engineering Science, 60, 95-102.
  • 16. Lin, B., Wen, Z.Y., Gu, Z.H., Huang, S.H., 2008. Morphology and Electrochemical Performance of Li[Ni1/3Co1/3Mn1/3]O2 Cathode Material by a Slurry Spray Drying Method, Journal of Power Sources, 175, 564-569.
  • 17. Panda, J., Sasmal, I., Nath, T.K., 2016. Magnetic and Optical Properties of Mn-doped ZnO Vertically Aligned Nanorods Synthesized by Hydrothermal Technique, AIP Advances, 6, 035118-10.
  • 18. Toloman, D., Mesaros, A., Popa, A., Raita, O., Silipas, T.D., Vasile, B.S., Pana, O., Giurgiu, L.M., 2013. Evidence by EPR of Ferromagnetic Phase in Mn-doped ZnO Nanoparticles Annealed at Different Temperatures, Journal of Alloys and Compounds. 551, 502–507.
  • 19. Urbieta, A., Fernández, P., Piqueras, J., 2012. Nanowires and Stacks of Nanoplates of Mn Doped ZnO Synthesized by Thermal Evaporation-deposition, Materials Chemistry and Physics, 132, 1119–1124.
  • 20. Ahmed, S.A., 2017. Structural, Optical, and Magnetic Properties of Mn-doped ZnO Samples, Results in Physics, 7, 604–610.
  • 21. Li, W., Wang, G., Chen, C., Liao, J., Li, Z., 2017. Enhanced Visible Light Photocatalytic Activity of ZnO Nanowires Doped with Mn2+ and Co2+ Ions, Nanomaterials 7, 1-11.

Püskürtmeli Kurutma ve Ardından Termal Bozunma ile Sentezlenen Mn Katkılı ZnO Nanotozların Antibakteriyel ve Optik Özellikleri

Year 2020, Volume: 35 Issue: 4, 1073 - 1082, 31.12.2020

Şeyma Duman Büşra Bulut Burak Özkal

https://doi.org/10.21605/cukurovaummfd.869176
Cited By: 2

Abstract

Homojen dağılımlı Mn katkılı ZnO nanotozlar, püskürtmeli kurutma ve termal bozunma ikili yöntemleri kullanılarak sentezlenmiştir. Sentez, çinko asetat tozları içeren püskürtmeli kurutma bulamacında gerçekleştirilmiş olup, ardından hazırlanan tozlar 300, 400 ve 500oC’de kalsine edimiştir. Sentez sırasında 0,01-0,05 M arasında farklı konsantrasyonlarda mangan (II) asetat ilave edilerek Mn katkısı sağlanmıştır. Elde edilen tozların karalterizasyonu gerçekleştirilmiştir. Faz analizinin sonuçları, Mn katkılı ZnO nanotozlarının, altıgen bir yapıda tek bir ZnO fazına sahip olduğunu ortaya çıkardı. Mikroyapısal ve UV- görünür karakterizasyon sonuçlarına göre Mn katkısı, ZnO nanotozlarının morfolojilerini ve optik özelliklerini değiştirmiştir. Ayrıca sonuçlar, Mn ilavesinin sentezlenmiş ZnO nanotozların antibakteriyel performansını önemli ölçüde artırabildiğini ortaya koymuştur.

Keywords

Mn katkılı ZnO Püskürtmeli kurutma Optik özellikler Antibakteriyel özellikler

References

  • 1. Ozgur U., Alivov Y.I., Liu C., Take A., Reshchikov M.A., Dogan S., Avrutin V., Cho S.J., Markoc H., 2005. A Comprehensive Review of ZnO Materials and Devices, Journal of Applied Physics, 98, 041301.
  • 2. Khosravi-Gandomani S., Yousefi R., Jamali- Sheini F., Huang N.M., 2014. Optical and Electrical Properties of P-type Ag-doped ZnO Nanostructures, Ceramics International, 40, 7957-7963.
  • 3. Yousefi, R., Jamli-Sheini, F., 2012. Effect of Chlorine Ion Concentration on Morphology and Optical Properties of Cl-doped ZnO Nanostructures, Ceramics International, 38(7), 5821-5825.
  • 4. Ravichandran, K., Karthika, K., Sakthivel, B., Jabena Begum, N., Snega, S., Swaminathan, K., Senthamilselvi, V., 2014. Tuning the Combined Magnetic and Antibacterial Properties of ZnO Nanopowders Through Mn Doping for Biomedical Applications, Journal of Magnetism and Magnetic Materials, 358-359, 50–55.
  • 5. Mote, V.D., Dargad, J.S., Purushotham, Y., Dole, B.N., 2015. Effect of Doping on Structural, Physical, Morphological and Optical Properties of Zn1-xMnxO Nano- particles, Ceramics International, 41, 15153–15161.
  • 6. Omri, K., El, Ghoul, J., Lemine, O.M., Bououdina, M., Zhang, B., El Mira, L., 2013. Magnetic and Optical Properties of Manganese Doped ZnO Nanoparticles Synthesized by Sol– gel Technique, Superlattices and Microstructures 60, 139–147.
  • 7. Ma, X., Wang, Z., 2011. The UV and Blue Light Emission Properties of Mn Doped ZnO Nanocrystals, Microelectronic Engineering, 88(10), 3168-3171.
  • 8. Bhat, S.V., Deepak, F.L., 2005. Tuning the Bandgap of ZnO by Substitution with Mn2+, Co2+ and Ni2+, Solid State Communications, 135(6), 345-347.
  • 9. Senthilkumaar, S., Rajendran, K., Banerjee, S., Chinic, T.K., Sengodan, V., 2008. Influence of Mn Doping on the Microstructure and Optical Property of ZnO, Materials Science in Semiconductor Processing, 11(1) 6-12.
  • 10. Vethanathan, S.J.K., Brightson, M., Sundar, S.M., Perumal, S., 2011. Synthesis of Mn Doped ZnO Nanocrystals by Solvothermal Route and its Characterization, Materials Chemistry and Physics, 125, 872–875.
  • 11. Jiang, Y.J., Wang, W., Jing, C.B., Cao, C.Y., Chu, J.H., 2011. Sol-gel Synthesis, Structure and Magnetic Properties of Mn-doped ZnO Diluted Magnetic Semiconductors, Materials Science and Engineering: B 176, 1301–1306.
  • 12. Yan, H.L., Wang, J.B., Zhong, X.L., 2011. Zn- catalyzed Growth Processes and Ferromagnetism of Mn-doped ZnO Nanorods on Si Substrate, Applied Surface Science, 257, 5017–5020.
  • 13. Duman, Ş., Ozkal, B., 2016. Powder State Characterization of ZnO/C and NiO/C Composite Nanopowders Synthesized Via Spray Drying Subsequent Thermal Decomposition, XIII. International Congress Winter Session ‘Machines, Technologies, Materials’ (MTM 2016), 14-17 September 2016, Varna – Bulgaria, 36-39.
  • 14. Duman, Ş., Ozkal, B., 2016. Effect of Dopant and Binder on the Formation of ZnO Powders During Thermal Decomposition of Spray Dried Zinc-acetate Based Granules, Journal of Optoelectronics and Advanced Materials, 18, 705-711.
  • 15. Bertrand, G., Roy, P., Filiatre, V., Coddet, C., 2005. Spray-dried Ceramic Powders: A Quantitative Correlation Between Slurry Characteristics and Shapes of the Granules, Chemical Engineering Science, 60, 95-102.
  • 16. Lin, B., Wen, Z.Y., Gu, Z.H., Huang, S.H., 2008. Morphology and Electrochemical Performance of Li[Ni1/3Co1/3Mn1/3]O2 Cathode Material by a Slurry Spray Drying Method, Journal of Power Sources, 175, 564-569.
  • 17. Panda, J., Sasmal, I., Nath, T.K., 2016. Magnetic and Optical Properties of Mn-doped ZnO Vertically Aligned Nanorods Synthesized by Hydrothermal Technique, AIP Advances, 6, 035118-10.
  • 18. Toloman, D., Mesaros, A., Popa, A., Raita, O., Silipas, T.D., Vasile, B.S., Pana, O., Giurgiu, L.M., 2013. Evidence by EPR of Ferromagnetic Phase in Mn-doped ZnO Nanoparticles Annealed at Different Temperatures, Journal of Alloys and Compounds. 551, 502–507.
  • 19. Urbieta, A., Fernández, P., Piqueras, J., 2012. Nanowires and Stacks of Nanoplates of Mn Doped ZnO Synthesized by Thermal Evaporation-deposition, Materials Chemistry and Physics, 132, 1119–1124.
  • 20. Ahmed, S.A., 2017. Structural, Optical, and Magnetic Properties of Mn-doped ZnO Samples, Results in Physics, 7, 604–610.
  • 21. Li, W., Wang, G., Chen, C., Liao, J., Li, Z., 2017. Enhanced Visible Light Photocatalytic Activity of ZnO Nanowires Doped with Mn2+ and Co2+ Ions, Nanomaterials 7, 1-11.
There are 21 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Şeyma Duman This is me 0000-0002-6685-5656

Büşra Bulut 0000-0002-9946-6729

Burak Özkal This is me 0000-0003-3431-2304

Publication Date December 31, 2020
Published in Issue Year 2020 Volume: 35 Issue: 4

Cite

APA Duman, Ş., Bulut, B., & Özkal, B. (2020). Antibacterial and Optical Properties of Mn Doped ZnO Nanopowders Synthesized via Spray Drying and Subsequent Thermal Decomposition. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 35(4), 1073-1082. https://doi.org/10.21605/cukurovaummfd.869176
AMA Duman Ş, Bulut B, Özkal B. Antibacterial and Optical Properties of Mn Doped ZnO Nanopowders Synthesized via Spray Drying and Subsequent Thermal Decomposition. cukurovaummfd. December 2020;35(4):1073-1082. doi:10.21605/cukurovaummfd.869176
Chicago Duman, Şeyma, Büşra Bulut, and Burak Özkal. “Antibacterial and Optical Properties of Mn Doped ZnO Nanopowders Synthesized via Spray Drying and Subsequent Thermal Decomposition”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 35, no. 4 (December 2020): 1073-82. https://doi.org/10.21605/cukurovaummfd.869176.
EndNote Duman Ş, Bulut B, Özkal B (December 1, 2020) Antibacterial and Optical Properties of Mn Doped ZnO Nanopowders Synthesized via Spray Drying and Subsequent Thermal Decomposition. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 35 4 1073–1082.
IEEE Ş. Duman, B. Bulut, and B. Özkal, “Antibacterial and Optical Properties of Mn Doped ZnO Nanopowders Synthesized via Spray Drying and Subsequent Thermal Decomposition”, cukurovaummfd, vol. 35, no. 4, pp. 1073–1082, 2020, doi: 10.21605/cukurovaummfd.869176.
ISNAD Duman, Şeyma et al. “Antibacterial and Optical Properties of Mn Doped ZnO Nanopowders Synthesized via Spray Drying and Subsequent Thermal Decomposition”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi 35/4 (December 2020), 1073-1082. https://doi.org/10.21605/cukurovaummfd.869176.
JAMA Duman Ş, Bulut B, Özkal B. Antibacterial and Optical Properties of Mn Doped ZnO Nanopowders Synthesized via Spray Drying and Subsequent Thermal Decomposition. cukurovaummfd. 2020;35:1073–1082.
MLA Duman, Şeyma et al. “Antibacterial and Optical Properties of Mn Doped ZnO Nanopowders Synthesized via Spray Drying and Subsequent Thermal Decomposition”. Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, vol. 35, no. 4, 2020, pp. 1073-82, doi:10.21605/cukurovaummfd.869176.
Vancouver Duman Ş, Bulut B, Özkal B. Antibacterial and Optical Properties of Mn Doped ZnO Nanopowders Synthesized via Spray Drying and Subsequent Thermal Decomposition. cukurovaummfd. 2020;35(4):1073-82.

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